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(2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide

The mol­ecule of the title compound, C(14)H(13)N(3)O, adopts an E conformation with respect to the azomethine C=N bond, and is roughly planar, with an r.m.s. deviation of the non-H atoms from the least-squares plane of 0.100 (2) Å and a dihedral angle between the terminal benzene rings of 5.74 (12)°...

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Detalles Bibliográficos
Autores principales: Layana, S. R., Sithambaresan, M., Siji, V. L., Sudarsanakumar, M. R., Suma, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011198/
https://www.ncbi.nlm.nih.gov/pubmed/24860389
http://dx.doi.org/10.1107/S1600536814008344
Descripción
Sumario:The mol­ecule of the title compound, C(14)H(13)N(3)O, adopts an E conformation with respect to the azomethine C=N bond, and is roughly planar, with an r.m.s. deviation of the non-H atoms from the least-squares plane of 0.100 (2) Å and a dihedral angle between the terminal benzene rings of 5.74 (12)°. An intramolecular N—H⋯N hydrogen bond closes an S(6) ring. In the crystal, mol­ecules are linked by the pairs of N—H⋯O hydrogen bonds into centrosymmetric dimers. Dimers related by translation along [010] form slanted stacks, the shortest C⋯C inter­molecular distance within the stack being 3.283 (3) Å. Weak C—H⋯π inter­actions link the stacks into a three-dimensional structure.