(2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide

The mol­ecule of the title compound, C(14)H(13)N(3)O, adopts an E conformation with respect to the azomethine C=N bond, and is roughly planar, with an r.m.s. deviation of the non-H atoms from the least-squares plane of 0.100 (2) Å and a dihedral angle between the terminal benzene rings of 5.74 (12)°...

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Detalles Bibliográficos
Autores principales: Layana, S. R., Sithambaresan, M., Siji, V. L., Sudarsanakumar, M. R., Suma, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011198/
https://www.ncbi.nlm.nih.gov/pubmed/24860389
http://dx.doi.org/10.1107/S1600536814008344
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author Layana, S. R.
Sithambaresan, M.
Siji, V. L.
Sudarsanakumar, M. R.
Suma, S.
author_facet Layana, S. R.
Sithambaresan, M.
Siji, V. L.
Sudarsanakumar, M. R.
Suma, S.
author_sort Layana, S. R.
collection PubMed
description The mol­ecule of the title compound, C(14)H(13)N(3)O, adopts an E conformation with respect to the azomethine C=N bond, and is roughly planar, with an r.m.s. deviation of the non-H atoms from the least-squares plane of 0.100 (2) Å and a dihedral angle between the terminal benzene rings of 5.74 (12)°. An intramolecular N—H⋯N hydrogen bond closes an S(6) ring. In the crystal, mol­ecules are linked by the pairs of N—H⋯O hydrogen bonds into centrosymmetric dimers. Dimers related by translation along [010] form slanted stacks, the shortest C⋯C inter­molecular distance within the stack being 3.283 (3) Å. Weak C—H⋯π inter­actions link the stacks into a three-dimensional structure.
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spelling pubmed-40111982014-05-23 (2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide Layana, S. R. Sithambaresan, M. Siji, V. L. Sudarsanakumar, M. R. Suma, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(14)H(13)N(3)O, adopts an E conformation with respect to the azomethine C=N bond, and is roughly planar, with an r.m.s. deviation of the non-H atoms from the least-squares plane of 0.100 (2) Å and a dihedral angle between the terminal benzene rings of 5.74 (12)°. An intramolecular N—H⋯N hydrogen bond closes an S(6) ring. In the crystal, mol­ecules are linked by the pairs of N—H⋯O hydrogen bonds into centrosymmetric dimers. Dimers related by translation along [010] form slanted stacks, the shortest C⋯C inter­molecular distance within the stack being 3.283 (3) Å. Weak C—H⋯π inter­actions link the stacks into a three-dimensional structure. International Union of Crystallography 2014-04-26 /pmc/articles/PMC4011198/ /pubmed/24860389 http://dx.doi.org/10.1107/S1600536814008344 Text en © Layana et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Layana, S. R.
Sithambaresan, M.
Siji, V. L.
Sudarsanakumar, M. R.
Suma, S.
(2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide
title (2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide
title_full (2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide
title_fullStr (2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide
title_full_unstemmed (2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide
title_short (2E)-2-Benzyl­idene-N-phenyl­hydrazinecarboxamide
title_sort (2e)-2-benzyl­idene-n-phenyl­hydrazinecarboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011198/
https://www.ncbi.nlm.nih.gov/pubmed/24860389
http://dx.doi.org/10.1107/S1600536814008344
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AT sumas 2e2benzylidenenphenylhydrazinecarboxamide

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