1-(3-Hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one

The stereochemistry and regioschemistry (exo) of the title compound, C(15)H(18)O(5), were determined by the X-ray analysis. The meth­oxy groups essentially lie in the plane of the benzene ring to which they are attached, as described by the C—O—C C torsion angles of −176.80 (12) and 4.67 (19)°. In t...

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Detalles Bibliográficos
Autores principales: Lough, Alan J., Nagireddy, Jaipal R., Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011200/
https://www.ncbi.nlm.nih.gov/pubmed/24860353
http://dx.doi.org/10.1107/S1600536814007764
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author Lough, Alan J.
Nagireddy, Jaipal R.
Tam, William
author_facet Lough, Alan J.
Nagireddy, Jaipal R.
Tam, William
author_sort Lough, Alan J.
collection PubMed
description The stereochemistry and regioschemistry (exo) of the title compound, C(15)H(18)O(5), were determined by the X-ray analysis. The meth­oxy groups essentially lie in the plane of the benzene ring to which they are attached, as described by the C—O—C C torsion angles of −176.80 (12) and 4.67 (19)°. In the crystal, O—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds link the mol­ecules, forming chains of R (2) (1)(8) rings along [010].
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spelling pubmed-40112002014-05-23 1-(3-Hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one Lough, Alan J. Nagireddy, Jaipal R. Tam, William Acta Crystallogr Sect E Struct Rep Online Organic Papers The stereochemistry and regioschemistry (exo) of the title compound, C(15)H(18)O(5), were determined by the X-ray analysis. The meth­oxy groups essentially lie in the plane of the benzene ring to which they are attached, as described by the C—O—C C torsion angles of −176.80 (12) and 4.67 (19)°. In the crystal, O—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds link the mol­ecules, forming chains of R (2) (1)(8) rings along [010]. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011200/ /pubmed/24860353 http://dx.doi.org/10.1107/S1600536814007764 Text en © Lough et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lough, Alan J.
Nagireddy, Jaipal R.
Tam, William
1-(3-Hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one
title 1-(3-Hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one
title_full 1-(3-Hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one
title_fullStr 1-(3-Hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one
title_full_unstemmed 1-(3-Hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one
title_short 1-(3-Hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one
title_sort 1-(3-hy­droxy-5,8-dimeth­oxy-4-methyl-1,2,3,4-tetra­hydro-1,4-ep­oxy­naphthalen-2-yl)ethan-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011200/
https://www.ncbi.nlm.nih.gov/pubmed/24860353
http://dx.doi.org/10.1107/S1600536814007764
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AT tamwilliam 13hydroxy58dimethoxy4methyl1234tetrahydro14epoxynaphthalen2ylethan1one

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