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Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate
The molecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011201/ https://www.ncbi.nlm.nih.gov/pubmed/24860347 http://dx.doi.org/10.1107/S1600536814007806 |
Sumario: | The molecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of 18.42 (16)°. Intramolecular N—H⋯Se hydrogen bonds are noted. Intermolecular C—H⋯Se interactions give rise to supramolecular chains extended along [100]. One severely disordered acetonitrile solvent molecule per asymmetric unit was treated with SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystal data take the presence of this molecule into account. |
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