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Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate

The mol­ecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of...

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Detalles Bibliográficos
Autores principales: Neuba, Adam, Schneider, Tobias, Flörke, Ulrich, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011201/
https://www.ncbi.nlm.nih.gov/pubmed/24860347
http://dx.doi.org/10.1107/S1600536814007806
Descripción
Sumario:The mol­ecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of 18.42 (16)°. Intra­molecular N—H⋯Se hydrogen bonds are noted. Inter­molecular C—H⋯Se inter­actions give rise to supra­molecular chains extended along [100]. One severely disordered aceto­nitrile solvent mol­ecule per asymmetric unit was treated with SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystal data take the presence of this mol­ecule into account.