Cargando…

Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate

The mol­ecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of...

Descripción completa

Detalles Bibliográficos
Autores principales: Neuba, Adam, Schneider, Tobias, Flörke, Ulrich, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011201/
https://www.ncbi.nlm.nih.gov/pubmed/24860347
http://dx.doi.org/10.1107/S1600536814007806
_version_ 1782314769427988480
author Neuba, Adam
Schneider, Tobias
Flörke, Ulrich
Henkel, Gerald
author_facet Neuba, Adam
Schneider, Tobias
Flörke, Ulrich
Henkel, Gerald
author_sort Neuba, Adam
collection PubMed
description The mol­ecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of 18.42 (16)°. Intra­molecular N—H⋯Se hydrogen bonds are noted. Inter­molecular C—H⋯Se inter­actions give rise to supra­molecular chains extended along [100]. One severely disordered aceto­nitrile solvent mol­ecule per asymmetric unit was treated with SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystal data take the presence of this mol­ecule into account.
format Online
Article
Text
id pubmed-4011201
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-40112012014-05-23 Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate Neuba, Adam Schneider, Tobias Flörke, Ulrich Henkel, Gerald Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of 18.42 (16)°. Intra­molecular N—H⋯Se hydrogen bonds are noted. Inter­molecular C—H⋯Se inter­actions give rise to supra­molecular chains extended along [100]. One severely disordered aceto­nitrile solvent mol­ecule per asymmetric unit was treated with SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystal data take the presence of this mol­ecule into account. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011201/ /pubmed/24860347 http://dx.doi.org/10.1107/S1600536814007806 Text en © Neuba et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Neuba, Adam
Schneider, Tobias
Flörke, Ulrich
Henkel, Gerald
Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate
title Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate
title_full Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate
title_fullStr Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate
title_full_unstemmed Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate
title_short Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate
title_sort bis{2-[(tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011201/
https://www.ncbi.nlm.nih.gov/pubmed/24860347
http://dx.doi.org/10.1107/S1600536814007806
work_keys_str_mv AT neubaadam bis2triphenylmethylaminophenyldiselenideacetonitrilemonosolvate
AT schneidertobias bis2triphenylmethylaminophenyldiselenideacetonitrilemonosolvate
AT florkeulrich bis2triphenylmethylaminophenyldiselenideacetonitrilemonosolvate
AT henkelgerald bis2triphenylmethylaminophenyldiselenideacetonitrilemonosolvate