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Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate
The molecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011201/ https://www.ncbi.nlm.nih.gov/pubmed/24860347 http://dx.doi.org/10.1107/S1600536814007806 |
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author | Neuba, Adam Schneider, Tobias Flörke, Ulrich Henkel, Gerald |
author_facet | Neuba, Adam Schneider, Tobias Flörke, Ulrich Henkel, Gerald |
author_sort | Neuba, Adam |
collection | PubMed |
description | The molecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of 18.42 (16)°. Intramolecular N—H⋯Se hydrogen bonds are noted. Intermolecular C—H⋯Se interactions give rise to supramolecular chains extended along [100]. One severely disordered acetonitrile solvent molecule per asymmetric unit was treated with SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystal data take the presence of this molecule into account. |
format | Online Article Text |
id | pubmed-4011201 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40112012014-05-23 Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate Neuba, Adam Schneider, Tobias Flörke, Ulrich Henkel, Gerald Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecular structure of the title compound, C(50)H(40)N(2)Se(2)·C(2)H(3)N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se—Se bond length of 2.3529 (6) Å and a C—Se—Se—C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of 18.42 (16)°. Intramolecular N—H⋯Se hydrogen bonds are noted. Intermolecular C—H⋯Se interactions give rise to supramolecular chains extended along [100]. One severely disordered acetonitrile solvent molecule per asymmetric unit was treated with SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystal data take the presence of this molecule into account. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011201/ /pubmed/24860347 http://dx.doi.org/10.1107/S1600536814007806 Text en © Neuba et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Neuba, Adam Schneider, Tobias Flörke, Ulrich Henkel, Gerald Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate |
title | Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate |
title_full | Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate |
title_fullStr | Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate |
title_full_unstemmed | Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate |
title_short | Bis{2-[(Triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate |
title_sort | bis{2-[(triphenylmethyl)amino]phenyl} diselenide acetonitrile monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011201/ https://www.ncbi.nlm.nih.gov/pubmed/24860347 http://dx.doi.org/10.1107/S1600536814007806 |
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