Bis(2,2′-bipyridyl-κ(2) N,N′)chloridonickel(II) nitrate trihydrate

In the title hydrated salt, [NiCl(C(10)H(8)N(2))(2)](NO(3))·3H(2)O, the Ni(2+) ion is coordinated by two 2,2′-bipyridyl (2,2′-bpy) ligands and a chloride ion in a trigonal–bipyramidal geometry. The chloride ion occupies an equatorial site and the dihedral angle between the 2,2′-bpy ring systems is 7...

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Detalles Bibliográficos
Autores principales: Boutebdja, Mehdi, Beghidja, Adel, Beghidja, Chahrazed, Setifi, Zouaoui, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011205/
https://www.ncbi.nlm.nih.gov/pubmed/24860319
http://dx.doi.org/10.1107/S1600536814009064
Descripción
Sumario:In the title hydrated salt, [NiCl(C(10)H(8)N(2))(2)](NO(3))·3H(2)O, the Ni(2+) ion is coordinated by two 2,2′-bipyridyl (2,2′-bpy) ligands and a chloride ion in a trigonal–bipyramidal geometry. The chloride ion occupies an equatorial site and the dihedral angle between the 2,2′-bpy ring systems is 72.02 (6)°. In the crystal, the components are linked by C—H⋯O and O—H⋯O hydrogen bonds and aromatic π–π stacking inter­actions [shortest centroid–centroid separation = 3.635 (2) Å], generating a three-dimensional network.