(±)-4,12,15,18,26-Penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate

The title compound, C(24)H(14)O(9)·2CH(3)OH, displays a chair-shaped form. The two di­hydro­indenone ring systems are located above and below the central fused-ring system, the dihedral angles between the mean planes of di­hydro­indenone ring systems and the mean plane of central fused-ring system a...

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Autores principales: Gil, Maayan, Almog, Joseph, Dubnikova, Faina, Bogoslavski, Benny, Cohen, Shmuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011206/
https://www.ncbi.nlm.nih.gov/pubmed/24860323
http://dx.doi.org/10.1107/S1600536814006643
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author Gil, Maayan
Almog, Joseph
Dubnikova, Faina
Bogoslavski, Benny
Cohen, Shmuel
author_facet Gil, Maayan
Almog, Joseph
Dubnikova, Faina
Bogoslavski, Benny
Cohen, Shmuel
author_sort Gil, Maayan
collection PubMed
description The title compound, C(24)H(14)O(9)·2CH(3)OH, displays a chair-shaped form. The two di­hydro­indenone ring systems are located above and below the central fused-ring system, the dihedral angles between the mean planes of di­hydro­indenone ring systems and the mean plane of central fused-ring system are 67.91 (5) and 73.52 (4)°, respectively. In the crystal, extensive O—H⋯O hydrogen bonds, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions link the mol­ecules into a three-dimensional supra­molecular architecture.
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spelling pubmed-40112062014-05-23 (±)-4,12,15,18,26-Penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate Gil, Maayan Almog, Joseph Dubnikova, Faina Bogoslavski, Benny Cohen, Shmuel Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(14)O(9)·2CH(3)OH, displays a chair-shaped form. The two di­hydro­indenone ring systems are located above and below the central fused-ring system, the dihedral angles between the mean planes of di­hydro­indenone ring systems and the mean plane of central fused-ring system are 67.91 (5) and 73.52 (4)°, respectively. In the crystal, extensive O—H⋯O hydrogen bonds, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions link the mol­ecules into a three-dimensional supra­molecular architecture. International Union of Crystallography 2014-04-02 /pmc/articles/PMC4011206/ /pubmed/24860323 http://dx.doi.org/10.1107/S1600536814006643 Text en © Gil et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gil, Maayan
Almog, Joseph
Dubnikova, Faina
Bogoslavski, Benny
Cohen, Shmuel
(±)-4,12,15,18,26-Penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate
title (±)-4,12,15,18,26-Penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate
title_full (±)-4,12,15,18,26-Penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate
title_fullStr (±)-4,12,15,18,26-Penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate
title_full_unstemmed (±)-4,12,15,18,26-Penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate
title_short (±)-4,12,15,18,26-Penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate
title_sort (±)-4,12,15,18,26-penta­hydroxy-13,17-dioxahepta­cyclo­[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa­cosa-1,3(14),6(11),7,9,15,19,21,23-nona­ene-5,25-dione methanol disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011206/
https://www.ncbi.nlm.nih.gov/pubmed/24860323
http://dx.doi.org/10.1107/S1600536814006643
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