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Poly[diaquatris(μ(6)-4,6-dioxo-1,4,5,6-tetra­hydro-1,3,5-triazine-2-carboxylato)tripotassium]

The asymmetric unit of the title compound, [K(3)(C(4)H(2)N(3)O(4))(3)(H(2)O)(2)](n), contains two potassium cations (one in general position, one located on a twofold rotation axis), one and a half oxonate anions (the other half generated by twofold symmetry) and one water mol­ecule. As a result of...

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Detalles Bibliográficos
Autores principales: Soudani, Sarra, Aubert, Emmanuel, Wenger, Emmanuel, Jelsch, Christian, Gautier-Luneau, Isabelle, Ben Nasr, Cherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011208/
https://www.ncbi.nlm.nih.gov/pubmed/24860308
http://dx.doi.org/10.1107/S1600536814007569
Descripción
Sumario:The asymmetric unit of the title compound, [K(3)(C(4)H(2)N(3)O(4))(3)(H(2)O)(2)](n), contains two potassium cations (one in general position, one located on a twofold rotation axis), one and a half oxonate anions (the other half generated by twofold symmetry) and one water mol­ecule. As a result of the twofold symmetry, one H atom of the symmetric anion is statistically occupied. Both potassium cations are surrounded by eight oxygen atoms in the form of distorted polyhedra. Adjacent cations are inter­connected by oxygen bridges, generating layers parallel to (100). The aromatic ring system of the oxonate anions link these layers into a network structure. The crystal packing is stabilized by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds, three of which are bifurcated. In addition, inter­molecular π–π stacking inter­actions exist between neighboring aromatic rings with a centroid–centroid distance of 3.241 (2) Å.