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(μ(2)-2-Methoxyethanol-κ(3) O (1):O (1),O (3))(2-methoxyethanol-κO (1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2) C (1):C (2))trimercury(II)
In the title compound, [Hg(3)(C(6)F(4))(3)(C(3)H(8)O(2))(2)], two O atoms from one 2-methoxyethanol ligand and one O atom from the second 2-methoxyethanol ligand coordinate three Hg(II) atoms [Hg—O = 2.765 (7)–2.890 (8) Å] in the trimeric organomercurial Lewis acid (o-C(6)F(4)Hg)(3). The hydrox...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011215/ https://www.ncbi.nlm.nih.gov/pubmed/24860301 http://dx.doi.org/10.1107/S1600536814006898 |
Sumario: | In the title compound, [Hg(3)(C(6)F(4))(3)(C(3)H(8)O(2))(2)], two O atoms from one 2-methoxyethanol ligand and one O atom from the second 2-methoxyethanol ligand coordinate three Hg(II) atoms [Hg—O = 2.765 (7)–2.890 (8) Å] in the trimeric organomercurial Lewis acid (o-C(6)F(4)Hg)(3). The hydroxy groups are involved in formation of intra- and intermolecular O—H⋯O hydrogen bonds; the latter link two molecules into centrosymmetric dimers. An extensive net of weak intermolecular C—H⋯F interactions further consolidates the crystal packing. |
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