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(μ(2)-2-Methoxyethanol-κ(3) O (1):O (1),O (3))(2-methoxyethanol-κO (1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2) C (1):C (2))trimercury(II)
In the title compound, [Hg(3)(C(6)F(4))(3)(C(3)H(8)O(2))(2)], two O atoms from one 2-methoxyethanol ligand and one O atom from the second 2-methoxyethanol ligand coordinate three Hg(II) atoms [Hg—O = 2.765 (7)–2.890 (8) Å] in the trimeric organomercurial Lewis acid (o-C(6)F(4)Hg)(3). The hydrox...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011215/ https://www.ncbi.nlm.nih.gov/pubmed/24860301 http://dx.doi.org/10.1107/S1600536814006898 |
| _version_ | 1782314772723662848 |
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| author | Castañeda, Raúl Draguta, Sergiu Yakovenko, Andrey Fonari, Marina Timofeeva, Tatiana |
| author_facet | Castañeda, Raúl Draguta, Sergiu Yakovenko, Andrey Fonari, Marina Timofeeva, Tatiana |
| author_sort | Castañeda, Raúl |
| collection | PubMed |
| description | In the title compound, [Hg(3)(C(6)F(4))(3)(C(3)H(8)O(2))(2)], two O atoms from one 2-methoxyethanol ligand and one O atom from the second 2-methoxyethanol ligand coordinate three Hg(II) atoms [Hg—O = 2.765 (7)–2.890 (8) Å] in the trimeric organomercurial Lewis acid (o-C(6)F(4)Hg)(3). The hydroxy groups are involved in formation of intra- and intermolecular O—H⋯O hydrogen bonds; the latter link two molecules into centrosymmetric dimers. An extensive net of weak intermolecular C—H⋯F interactions further consolidates the crystal packing. |
| format | Online Article Text |
| id | pubmed-4011215 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40112152014-05-23 (μ(2)-2-Methoxyethanol-κ(3) O (1):O (1),O (3))(2-methoxyethanol-κO (1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2) C (1):C (2))trimercury(II) Castañeda, Raúl Draguta, Sergiu Yakovenko, Andrey Fonari, Marina Timofeeva, Tatiana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(3)(C(6)F(4))(3)(C(3)H(8)O(2))(2)], two O atoms from one 2-methoxyethanol ligand and one O atom from the second 2-methoxyethanol ligand coordinate three Hg(II) atoms [Hg—O = 2.765 (7)–2.890 (8) Å] in the trimeric organomercurial Lewis acid (o-C(6)F(4)Hg)(3). The hydroxy groups are involved in formation of intra- and intermolecular O—H⋯O hydrogen bonds; the latter link two molecules into centrosymmetric dimers. An extensive net of weak intermolecular C—H⋯F interactions further consolidates the crystal packing. International Union of Crystallography 2014-04-05 /pmc/articles/PMC4011215/ /pubmed/24860301 http://dx.doi.org/10.1107/S1600536814006898 Text en © Castañeda et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Castañeda, Raúl Draguta, Sergiu Yakovenko, Andrey Fonari, Marina Timofeeva, Tatiana (μ(2)-2-Methoxyethanol-κ(3) O (1):O (1),O (3))(2-methoxyethanol-κO (1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2) C (1):C (2))trimercury(II) |
| title | (μ(2)-2-Methoxyethanol-κ(3)
O
(1):O
(1),O
(3))(2-methoxyethanol-κO
(1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2)
C
(1):C
(2))trimercury(II) |
| title_full | (μ(2)-2-Methoxyethanol-κ(3)
O
(1):O
(1),O
(3))(2-methoxyethanol-κO
(1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2)
C
(1):C
(2))trimercury(II) |
| title_fullStr | (μ(2)-2-Methoxyethanol-κ(3)
O
(1):O
(1),O
(3))(2-methoxyethanol-κO
(1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2)
C
(1):C
(2))trimercury(II) |
| title_full_unstemmed | (μ(2)-2-Methoxyethanol-κ(3)
O
(1):O
(1),O
(3))(2-methoxyethanol-κO
(1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2)
C
(1):C
(2))trimercury(II) |
| title_short | (μ(2)-2-Methoxyethanol-κ(3)
O
(1):O
(1),O
(3))(2-methoxyethanol-κO
(1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2)
C
(1):C
(2))trimercury(II) |
| title_sort | (μ(2)-2-methoxyethanol-κ(3)
o
(1):o
(1),o
(3))(2-methoxyethanol-κo
(1))tris(μ(2)-3,4,5,6-tetrafluoro-o-phenylene-κ(2)
c
(1):c
(2))trimercury(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011215/ https://www.ncbi.nlm.nih.gov/pubmed/24860301 http://dx.doi.org/10.1107/S1600536814006898 |
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