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(2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I)
The title salt, [K(C(18)H(36)N(2)O(6))][Co(CO)(4)], is an example of a classical carbonylmetalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C—O bond lengths and C—Co—C angles, the anion is unperturbed by t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011216/ https://www.ncbi.nlm.nih.gov/pubmed/24860312 http://dx.doi.org/10.1107/S1600536814006758 |
| _version_ | 1782314772961689600 |
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| author | Brennessel, William W. Ellis, John E. |
| author_facet | Brennessel, William W. Ellis, John E. |
| author_sort | Brennessel, William W. |
| collection | PubMed |
| description | The title salt, [K(C(18)H(36)N(2)O(6))][Co(CO)(4)], is an example of a classical carbonylmetalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C—O bond lengths and C—Co—C angles, the anion is unperturbed by the cation, which is normal for an alkali metal fully encased by a cryptand cage. |
| format | Online Article Text |
| id | pubmed-4011216 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40112162014-05-23 (2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I) Brennessel, William W. Ellis, John E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, [K(C(18)H(36)N(2)O(6))][Co(CO)(4)], is an example of a classical carbonylmetalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C—O bond lengths and C—Co—C angles, the anion is unperturbed by the cation, which is normal for an alkali metal fully encased by a cryptand cage. International Union of Crystallography 2014-04-16 /pmc/articles/PMC4011216/ /pubmed/24860312 http://dx.doi.org/10.1107/S1600536814006758 Text en © Brennessel and Ellis 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Brennessel, William W. Ellis, John E. (2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I) |
| title | (2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I) |
| title_full | (2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I) |
| title_fullStr | (2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I) |
| title_full_unstemmed | (2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I) |
| title_short | (2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I) |
| title_sort | (2.2.2-cryptand)potassium tetracarbonylcobaltate(−i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011216/ https://www.ncbi.nlm.nih.gov/pubmed/24860312 http://dx.doi.org/10.1107/S1600536814006758 |
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