Methyl ({[(4E)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate

In the title compound, C(22)H(26)N(2)O(3), the piperidine ring exhibits a chair conformation. The phenyl rings attached to the piperidine at the 2- and 6-positions have axial orientations. These rings make a dihedral angle of 49.75 (11)°. The amino­oxy acetate group attached at the 4-position has an...

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Autores principales: Mohandas, T., Pillai, M. Velayutham, Vidhyasagar, T., Pasupathy, A., Sakthivel, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011218/
https://www.ncbi.nlm.nih.gov/pubmed/24860328
http://dx.doi.org/10.1107/S1600536814006667
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author Mohandas, T.
Pillai, M. Velayutham
Vidhyasagar, T.
Pasupathy, A.
Sakthivel, P.
author_facet Mohandas, T.
Pillai, M. Velayutham
Vidhyasagar, T.
Pasupathy, A.
Sakthivel, P.
author_sort Mohandas, T.
collection PubMed
description In the title compound, C(22)H(26)N(2)O(3), the piperidine ring exhibits a chair conformation. The phenyl rings attached to the piperidine at the 2- and 6-positions have axial orientations. These rings make a dihedral angle of 49.75 (11)°. The amino­oxy acetate group attached at the 4-position has an equatorial orientation. In the crystal, inversion dimers linked by pairs of C—H⋯π inter­actions occur.
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spelling pubmed-40112182014-05-23 Methyl ({[(4E)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate Mohandas, T. Pillai, M. Velayutham Vidhyasagar, T. Pasupathy, A. Sakthivel, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(26)N(2)O(3), the piperidine ring exhibits a chair conformation. The phenyl rings attached to the piperidine at the 2- and 6-positions have axial orientations. These rings make a dihedral angle of 49.75 (11)°. The amino­oxy acetate group attached at the 4-position has an equatorial orientation. In the crystal, inversion dimers linked by pairs of C—H⋯π inter­actions occur. International Union of Crystallography 2014-04-02 /pmc/articles/PMC4011218/ /pubmed/24860328 http://dx.doi.org/10.1107/S1600536814006667 Text en © Mohandas et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohandas, T.
Pillai, M. Velayutham
Vidhyasagar, T.
Pasupathy, A.
Sakthivel, P.
Methyl ({[(4E)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate
title Methyl ({[(4E)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate
title_full Methyl ({[(4E)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate
title_fullStr Methyl ({[(4E)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate
title_full_unstemmed Methyl ({[(4E)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate
title_short Methyl ({[(4E)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate
title_sort methyl ({[(4e)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-yl­idene]amino}­oxy)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011218/
https://www.ncbi.nlm.nih.gov/pubmed/24860328
http://dx.doi.org/10.1107/S1600536814006667
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AT vidhyasagart methyl4e13dimethyl26diphenylpiperidin4ylideneaminooxyacetate
AT pasupathya methyl4e13dimethyl26diphenylpiperidin4ylideneaminooxyacetate
AT sakthivelp methyl4e13dimethyl26diphenylpiperidin4ylideneaminooxyacetate

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