(4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II)

In the title compound, [Pd(CF(3))(C(6)H(4)F)(C(6)H(16)N(2))], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand and by one C atom each from a 4-fluoro­phenyl and a tri­fluoro­methyl ligand, in a distorted rectangular-planar geometry, with...

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Detalles Bibliográficos
Autores principales: Du, Youzhi, Zheng, ChangGe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011221/
https://www.ncbi.nlm.nih.gov/pubmed/24860311
http://dx.doi.org/10.1107/S1600536814007855
Descripción
Sumario:In the title compound, [Pd(CF(3))(C(6)H(4)F)(C(6)H(16)N(2))], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand and by one C atom each from a 4-fluoro­phenyl and a tri­fluoro­methyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the Pd(II) atom range from 83.14 (10) to 97.25 (12)°.

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