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(4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II)

In the title compound, [Pd(CF(3))(C(6)H(4)F)(C(6)H(16)N(2))], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand and by one C atom each from a 4-fluoro­phenyl and a tri­fluoro­methyl ligand, in a distorted rectangular-planar geometry, with...

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Detalles Bibliográficos
Autores principales: Du, Youzhi, Zheng, ChangGe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011221/
https://www.ncbi.nlm.nih.gov/pubmed/24860311
http://dx.doi.org/10.1107/S1600536814007855
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author Du, Youzhi
Zheng, ChangGe
author_facet Du, Youzhi
Zheng, ChangGe
author_sort Du, Youzhi
collection PubMed
description In the title compound, [Pd(CF(3))(C(6)H(4)F)(C(6)H(16)N(2))], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand and by one C atom each from a 4-fluoro­phenyl and a tri­fluoro­methyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the Pd(II) atom range from 83.14 (10) to 97.25 (12)°.
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spelling pubmed-40112212014-05-23 (4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II) Du, Youzhi Zheng, ChangGe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(CF(3))(C(6)H(4)F)(C(6)H(16)N(2))], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand and by one C atom each from a 4-fluoro­phenyl and a tri­fluoro­methyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the Pd(II) atom range from 83.14 (10) to 97.25 (12)°. International Union of Crystallography 2014-04-16 /pmc/articles/PMC4011221/ /pubmed/24860311 http://dx.doi.org/10.1107/S1600536814007855 Text en © Du and Zheng 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Du, Youzhi
Zheng, ChangGe
(4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II)
title (4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II)
title_full (4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II)
title_fullStr (4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II)
title_full_unstemmed (4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II)
title_short (4-Fluoro­phen­yl-κC)(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)(tri­fluoro­meth­yl-κC)palladium(II)
title_sort (4-fluoro­phen­yl-κc)(n,n,n′,n′-tetra­methyl­ethylenedi­amine-κ(2) n,n′)(tri­fluoro­meth­yl-κc)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011221/
https://www.ncbi.nlm.nih.gov/pubmed/24860311
http://dx.doi.org/10.1107/S1600536814007855
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