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(4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)(trifluoromethyl-κC)palladium(II)
In the title compound, [Pd(CF(3))(C(6)H(4)F)(C(6)H(16)N(2))], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and by one C atom each from a 4-fluorophenyl and a trifluoromethyl ligand, in a distorted rectangular-planar geometry, with...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011221/ https://www.ncbi.nlm.nih.gov/pubmed/24860311 http://dx.doi.org/10.1107/S1600536814007855 |
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author | Du, Youzhi Zheng, ChangGe |
author_facet | Du, Youzhi Zheng, ChangGe |
author_sort | Du, Youzhi |
collection | PubMed |
description | In the title compound, [Pd(CF(3))(C(6)H(4)F)(C(6)H(16)N(2))], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and by one C atom each from a 4-fluorophenyl and a trifluoromethyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the Pd(II) atom range from 83.14 (10) to 97.25 (12)°. |
format | Online Article Text |
id | pubmed-4011221 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40112212014-05-23 (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)(trifluoromethyl-κC)palladium(II) Du, Youzhi Zheng, ChangGe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(CF(3))(C(6)H(4)F)(C(6)H(16)N(2))], the Pd(II) cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and by one C atom each from a 4-fluorophenyl and a trifluoromethyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the Pd(II) atom range from 83.14 (10) to 97.25 (12)°. International Union of Crystallography 2014-04-16 /pmc/articles/PMC4011221/ /pubmed/24860311 http://dx.doi.org/10.1107/S1600536814007855 Text en © Du and Zheng 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Du, Youzhi Zheng, ChangGe (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)(trifluoromethyl-κC)palladium(II) |
title | (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)(trifluoromethyl-κC)palladium(II) |
title_full | (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)(trifluoromethyl-κC)palladium(II) |
title_fullStr | (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)(trifluoromethyl-κC)palladium(II) |
title_full_unstemmed | (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)(trifluoromethyl-κC)palladium(II) |
title_short | (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)(trifluoromethyl-κC)palladium(II) |
title_sort | (4-fluorophenyl-κc)(n,n,n′,n′-tetramethylethylenediamine-κ(2)
n,n′)(trifluoromethyl-κc)palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011221/ https://www.ncbi.nlm.nih.gov/pubmed/24860311 http://dx.doi.org/10.1107/S1600536814007855 |
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