Cargando…
β-d-Gulose
The title compound, C(6)H(12)O(6), a C-3 position epimer of d-galactose, crystallized from an aqueous solution, was confirmed as β-d-pyranose with a (4) C (1) (C1) conformation. In the crystal, O—H⋯O hydrogen bonds between the hydroxy groups at the C-1 and C-6 positions connect molecules into a t...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011222/ https://www.ncbi.nlm.nih.gov/pubmed/24860374 http://dx.doi.org/10.1107/S1600536814008046 |
_version_ | 1782314774352101376 |
---|---|
author | Ishii, Tomohiko Ohga, Shunsuke Fukada, Kazuhiro Morimoto, Kenji Sakane, Genta |
author_facet | Ishii, Tomohiko Ohga, Shunsuke Fukada, Kazuhiro Morimoto, Kenji Sakane, Genta |
author_sort | Ishii, Tomohiko |
collection | PubMed |
description | The title compound, C(6)H(12)O(6), a C-3 position epimer of d-galactose, crystallized from an aqueous solution, was confirmed as β-d-pyranose with a (4) C (1) (C1) conformation. In the crystal, O—H⋯O hydrogen bonds between the hydroxy groups at the C-1 and C-6 positions connect molecules into a tape structure with an R (3) (3)(11) ring motif running along the a-axis direction. The tapes are connected by further O—H⋯O hydrogen bonds, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-4011222 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40112222014-05-23 β-d-Gulose Ishii, Tomohiko Ohga, Shunsuke Fukada, Kazuhiro Morimoto, Kenji Sakane, Genta Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(12)O(6), a C-3 position epimer of d-galactose, crystallized from an aqueous solution, was confirmed as β-d-pyranose with a (4) C (1) (C1) conformation. In the crystal, O—H⋯O hydrogen bonds between the hydroxy groups at the C-1 and C-6 positions connect molecules into a tape structure with an R (3) (3)(11) ring motif running along the a-axis direction. The tapes are connected by further O—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2014-04-16 /pmc/articles/PMC4011222/ /pubmed/24860374 http://dx.doi.org/10.1107/S1600536814008046 Text en © Ishii et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ishii, Tomohiko Ohga, Shunsuke Fukada, Kazuhiro Morimoto, Kenji Sakane, Genta β-d-Gulose |
title | β-d-Gulose |
title_full | β-d-Gulose |
title_fullStr | β-d-Gulose |
title_full_unstemmed | β-d-Gulose |
title_short | β-d-Gulose |
title_sort | β-d-gulose |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011222/ https://www.ncbi.nlm.nih.gov/pubmed/24860374 http://dx.doi.org/10.1107/S1600536814008046 |
work_keys_str_mv | AT ishiitomohiko bdgulose AT ohgashunsuke bdgulose AT fukadakazuhiro bdgulose AT morimotokenji bdgulose AT sakanegenta bdgulose |