β-d-Gulose

The title compound, C(6)H(12)O(6), a C-3 position epimer of d-galactose, crystallized from an aqueous solution, was confirmed as β-d-pyran­ose with a (4) C (1) (C1) conformation. In the crystal, O—H⋯O hydrogen bonds between the hy­droxy groups at the C-1 and C-6 positions connect mol­ecules into a t...

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Autores principales: Ishii, Tomohiko, Ohga, Shunsuke, Fukada, Kazuhiro, Morimoto, Kenji, Sakane, Genta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011222/
https://www.ncbi.nlm.nih.gov/pubmed/24860374
http://dx.doi.org/10.1107/S1600536814008046
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author Ishii, Tomohiko
Ohga, Shunsuke
Fukada, Kazuhiro
Morimoto, Kenji
Sakane, Genta
author_facet Ishii, Tomohiko
Ohga, Shunsuke
Fukada, Kazuhiro
Morimoto, Kenji
Sakane, Genta
author_sort Ishii, Tomohiko
collection PubMed
description The title compound, C(6)H(12)O(6), a C-3 position epimer of d-galactose, crystallized from an aqueous solution, was confirmed as β-d-pyran­ose with a (4) C (1) (C1) conformation. In the crystal, O—H⋯O hydrogen bonds between the hy­droxy groups at the C-1 and C-6 positions connect mol­ecules into a tape structure with an R (3) (3)(11) ring motif running along the a-axis direction. The tapes are connected by further O—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-40112222014-05-23 β-d-Gulose Ishii, Tomohiko Ohga, Shunsuke Fukada, Kazuhiro Morimoto, Kenji Sakane, Genta Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(12)O(6), a C-3 position epimer of d-galactose, crystallized from an aqueous solution, was confirmed as β-d-pyran­ose with a (4) C (1) (C1) conformation. In the crystal, O—H⋯O hydrogen bonds between the hy­droxy groups at the C-1 and C-6 positions connect mol­ecules into a tape structure with an R (3) (3)(11) ring motif running along the a-axis direction. The tapes are connected by further O—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2014-04-16 /pmc/articles/PMC4011222/ /pubmed/24860374 http://dx.doi.org/10.1107/S1600536814008046 Text en © Ishii et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ishii, Tomohiko
Ohga, Shunsuke
Fukada, Kazuhiro
Morimoto, Kenji
Sakane, Genta
β-d-Gulose
title β-d-Gulose
title_full β-d-Gulose
title_fullStr β-d-Gulose
title_full_unstemmed β-d-Gulose
title_short β-d-Gulose
title_sort β-d-gulose
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011222/
https://www.ncbi.nlm.nih.gov/pubmed/24860374
http://dx.doi.org/10.1107/S1600536814008046
work_keys_str_mv AT ishiitomohiko bdgulose
AT ohgashunsuke bdgulose
AT fukadakazuhiro bdgulose
AT morimotokenji bdgulose
AT sakanegenta bdgulose

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