(Z)-N-[1-(Aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline

The title compound, C(10)H(8)BrF(3)N(2), crystallizes with two independent mol­ecules in the asymmetric unit, which can be considered as being related by a pseudo-inversion center, so their conformations are different; the corresponding N=C—N—C torsion angles are 54.6 (5) and −50.5 (5)°. In the crys...

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Autores principales: Bunev, Alexander S., Vasiliev, Maksim A., Ostapenko, Gennady I., Peregudov, Alexander S., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011223/
https://www.ncbi.nlm.nih.gov/pubmed/24860358
http://dx.doi.org/10.1107/S1600536814007867
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author Bunev, Alexander S.
Vasiliev, Maksim A.
Ostapenko, Gennady I.
Peregudov, Alexander S.
Khrustalev, Victor N.
author_facet Bunev, Alexander S.
Vasiliev, Maksim A.
Ostapenko, Gennady I.
Peregudov, Alexander S.
Khrustalev, Victor N.
author_sort Bunev, Alexander S.
collection PubMed
description The title compound, C(10)H(8)BrF(3)N(2), crystallizes with two independent mol­ecules in the asymmetric unit, which can be considered as being related by a pseudo-inversion center, so their conformations are different; the corresponding N=C—N—C torsion angles are 54.6 (5) and −50.5 (5)°. In the crystal, mol­ecules related by translation in [001] inter­act through short inter­molecular Br⋯F contacts [3.276 (2) and 3.284 (2) Å], thus forming two types of crystallographically independent chains.
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spelling pubmed-40112232014-05-23 (Z)-N-[1-(Aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline Bunev, Alexander S. Vasiliev, Maksim A. Ostapenko, Gennady I. Peregudov, Alexander S. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(8)BrF(3)N(2), crystallizes with two independent mol­ecules in the asymmetric unit, which can be considered as being related by a pseudo-inversion center, so their conformations are different; the corresponding N=C—N—C torsion angles are 54.6 (5) and −50.5 (5)°. In the crystal, mol­ecules related by translation in [001] inter­act through short inter­molecular Br⋯F contacts [3.276 (2) and 3.284 (2) Å], thus forming two types of crystallographically independent chains. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011223/ /pubmed/24860358 http://dx.doi.org/10.1107/S1600536814007867 Text en © Bunev et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bunev, Alexander S.
Vasiliev, Maksim A.
Ostapenko, Gennady I.
Peregudov, Alexander S.
Khrustalev, Victor N.
(Z)-N-[1-(Aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline
title (Z)-N-[1-(Aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline
title_full (Z)-N-[1-(Aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline
title_fullStr (Z)-N-[1-(Aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline
title_full_unstemmed (Z)-N-[1-(Aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline
title_short (Z)-N-[1-(Aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline
title_sort (z)-n-[1-(aziridin-1-yl)-2,2,2-tri­fluoro­ethyl­idene]-4-bromo­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011223/
https://www.ncbi.nlm.nih.gov/pubmed/24860358
http://dx.doi.org/10.1107/S1600536814007867
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