Tri­benzyl­ammonium chloride

Single crystals of the title salt, C(21)H(21)NH(+)·Cl(−), were isolated as a side product from the reaction involving [(C(6)H(5)CH(2))(3)NH](2)[HPO(4)] and Sn(CH(3))(3)Cl in ethanol. Both the cation and the anion are situated on a threefold rotation axis. The central N atom in the cation has a sligh...

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Detalles Bibliográficos
Autores principales: Diallo, Waly, Diop, Libasse, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011225/
https://www.ncbi.nlm.nih.gov/pubmed/24860409
http://dx.doi.org/10.1107/S1600536814009246
Descripción
Sumario:Single crystals of the title salt, C(21)H(21)NH(+)·Cl(−), were isolated as a side product from the reaction involving [(C(6)H(5)CH(2))(3)NH](2)[HPO(4)] and Sn(CH(3))(3)Cl in ethanol. Both the cation and the anion are situated on a threefold rotation axis. The central N atom in the cation has a slightly distorted tetra­hedral environment, with angles ranging from 107.7 to 111.16 (10)°. In the crystal, the tri­benzyl­ammonium cations and chloride anions are linked through N—H⋯Cl and C—H⋯Cl hydrogen bonds, leading to the formation of infinite chains along [001]. The crystal studied was a merohedral twin.

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