Tri­benzyl­ammonium chloride

Single crystals of the title salt, C(21)H(21)NH(+)·Cl(−), were isolated as a side product from the reaction involving [(C(6)H(5)CH(2))(3)NH](2)[HPO(4)] and Sn(CH(3))(3)Cl in ethanol. Both the cation and the anion are situated on a threefold rotation axis. The central N atom in the cation has a sligh...

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Autores principales: Diallo, Waly, Diop, Libasse, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011225/
https://www.ncbi.nlm.nih.gov/pubmed/24860409
http://dx.doi.org/10.1107/S1600536814009246
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author Diallo, Waly
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
author_facet Diallo, Waly
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
author_sort Diallo, Waly
collection PubMed
description Single crystals of the title salt, C(21)H(21)NH(+)·Cl(−), were isolated as a side product from the reaction involving [(C(6)H(5)CH(2))(3)NH](2)[HPO(4)] and Sn(CH(3))(3)Cl in ethanol. Both the cation and the anion are situated on a threefold rotation axis. The central N atom in the cation has a slightly distorted tetra­hedral environment, with angles ranging from 107.7 to 111.16 (10)°. In the crystal, the tri­benzyl­ammonium cations and chloride anions are linked through N—H⋯Cl and C—H⋯Cl hydrogen bonds, leading to the formation of infinite chains along [001]. The crystal studied was a merohedral twin.
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spelling pubmed-40112252014-05-23 Tri­benzyl­ammonium chloride Diallo, Waly Diop, Libasse Plasseraud, Laurent Cattey, Hélène Acta Crystallogr Sect E Struct Rep Online Organic Papers Single crystals of the title salt, C(21)H(21)NH(+)·Cl(−), were isolated as a side product from the reaction involving [(C(6)H(5)CH(2))(3)NH](2)[HPO(4)] and Sn(CH(3))(3)Cl in ethanol. Both the cation and the anion are situated on a threefold rotation axis. The central N atom in the cation has a slightly distorted tetra­hedral environment, with angles ranging from 107.7 to 111.16 (10)°. In the crystal, the tri­benzyl­ammonium cations and chloride anions are linked through N—H⋯Cl and C—H⋯Cl hydrogen bonds, leading to the formation of infinite chains along [001]. The crystal studied was a merohedral twin. International Union of Crystallography 2014-04-30 /pmc/articles/PMC4011225/ /pubmed/24860409 http://dx.doi.org/10.1107/S1600536814009246 Text en © Diallo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Diallo, Waly
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
Tri­benzyl­ammonium chloride
title Tri­benzyl­ammonium chloride
title_full Tri­benzyl­ammonium chloride
title_fullStr Tri­benzyl­ammonium chloride
title_full_unstemmed Tri­benzyl­ammonium chloride
title_short Tri­benzyl­ammonium chloride
title_sort tri­benzyl­ammonium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011225/
https://www.ncbi.nlm.nih.gov/pubmed/24860409
http://dx.doi.org/10.1107/S1600536814009246
work_keys_str_mv AT diallowaly tribenzylammoniumchloride
AT dioplibasse tribenzylammoniumchloride
AT plasseraudlaurent tribenzylammoniumchloride
AT catteyhelene tribenzylammoniumchloride

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