N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide

The title compound, C(11)H(8)N(2)O(3)S, shows two mol­ecules per asymmetric unit, with the dihedral angles between the benzene and thio­phene rings of 13.53 (6) and 8.50 (5)° being a notable difference between them. An intra­molecular N—H⋯O hydrogen-bond in each mol­ecule generates an S(6) ring moti...

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Detalles Bibliográficos
Autores principales: Moreno-Fuquen, Rodolfo, Azcárate, Alexis, Kennedy, Alan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011230/
https://www.ncbi.nlm.nih.gov/pubmed/24860404
http://dx.doi.org/10.1107/S160053681400912X
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author Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
author_facet Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
author_sort Moreno-Fuquen, Rodolfo
collection PubMed
description The title compound, C(11)H(8)N(2)O(3)S, shows two mol­ecules per asymmetric unit, with the dihedral angles between the benzene and thio­phene rings of 13.53 (6) and 8.50 (5)° being a notable difference between them. An intra­molecular N—H⋯O hydrogen-bond in each mol­ecule generates an S(6) ring motif. The crystal packing shows no classical hydrogen bonds with the mol­ecules being packed to form weak C—H⋯O and C—H⋯S inter­actions leading to R (2) (2)(9) and R (4) (4)(25) rings which are edge-shared, giving layers parallel to (010).
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spelling pubmed-40112302014-05-23 N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide Moreno-Fuquen, Rodolfo Azcárate, Alexis Kennedy, Alan R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(8)N(2)O(3)S, shows two mol­ecules per asymmetric unit, with the dihedral angles between the benzene and thio­phene rings of 13.53 (6) and 8.50 (5)° being a notable difference between them. An intra­molecular N—H⋯O hydrogen-bond in each mol­ecule generates an S(6) ring motif. The crystal packing shows no classical hydrogen bonds with the mol­ecules being packed to form weak C—H⋯O and C—H⋯S inter­actions leading to R (2) (2)(9) and R (4) (4)(25) rings which are edge-shared, giving layers parallel to (010). International Union of Crystallography 2014-04-26 /pmc/articles/PMC4011230/ /pubmed/24860404 http://dx.doi.org/10.1107/S160053681400912X Text en © Moreno-Fuquen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide
title N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide
title_full N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide
title_fullStr N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide
title_full_unstemmed N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide
title_short N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide
title_sort n-(2-nitro­phen­yl)thio­phene-2-carbox­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011230/
https://www.ncbi.nlm.nih.gov/pubmed/24860404
http://dx.doi.org/10.1107/S160053681400912X
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AT kennedyalanr n2nitrophenylthiophene2carboxamide

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