(1S,2R,3S,6S,7R)-3,7,11,11-Tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol

The title compound, C(15)H(26)O(2), was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzo­cyclo­heptene), which was isolated from the Atlas cedar (cedrus atlantica). The mol­ecule is built up from a seven-membered ring to which a six- and a three-membered ring are...

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Autores principales: Loubidi, Mohamed, Benharref, Ahmed, El Ammari, Lahcen, Saadi, Mohamed, Berraho, Moha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011231/
https://www.ncbi.nlm.nih.gov/pubmed/24860392
http://dx.doi.org/10.1107/S1600536814008642
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author Loubidi, Mohamed
Benharref, Ahmed
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
author_facet Loubidi, Mohamed
Benharref, Ahmed
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
author_sort Loubidi, Mohamed
collection PubMed
description The title compound, C(15)H(26)O(2), was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzo­cyclo­heptene), which was isolated from the Atlas cedar (cedrus atlantica). The mol­ecule is built up from a seven-membered ring to which a six- and a three-membered ring are fused. The seven- and six-membered rings each have a twist-boat conformation. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules into zigzag chains running along the b-axis direction.
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spelling pubmed-40112312014-05-23 (1S,2R,3S,6S,7R)-3,7,11,11-Tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol Loubidi, Mohamed Benharref, Ahmed El Ammari, Lahcen Saadi, Mohamed Berraho, Moha Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(26)O(2), was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzo­cyclo­heptene), which was isolated from the Atlas cedar (cedrus atlantica). The mol­ecule is built up from a seven-membered ring to which a six- and a three-membered ring are fused. The seven- and six-membered rings each have a twist-boat conformation. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules into zigzag chains running along the b-axis direction. International Union of Crystallography 2014-04-26 /pmc/articles/PMC4011231/ /pubmed/24860392 http://dx.doi.org/10.1107/S1600536814008642 Text en © Loubidi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Loubidi, Mohamed
Benharref, Ahmed
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
(1S,2R,3S,6S,7R)-3,7,11,11-Tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol
title (1S,2R,3S,6S,7R)-3,7,11,11-Tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol
title_full (1S,2R,3S,6S,7R)-3,7,11,11-Tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol
title_fullStr (1S,2R,3S,6S,7R)-3,7,11,11-Tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol
title_full_unstemmed (1S,2R,3S,6S,7R)-3,7,11,11-Tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol
title_short (1S,2R,3S,6S,7R)-3,7,11,11-Tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol
title_sort (1s,2r,3s,6s,7r)-3,7,11,11-tetra­methyl-6,7-epoxybi­cyclo­[5.4.0]undecane-2-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011231/
https://www.ncbi.nlm.nih.gov/pubmed/24860392
http://dx.doi.org/10.1107/S1600536814008642
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