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1-Methyl-3-phenylthiourea
The title compound, C(8)H(10)N(2)S, was prepared by reaction of methylamine solution, KOH and phenyl-isothiocyanate in ethanol. It adopts a syn-Me and anti-Ph conformation relative to the C=S double bond. The dihedral angle between the N—C(=S)—N thiourea and phenyl planes is 67.83 (6)°. In the c...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011236/ https://www.ncbi.nlm.nih.gov/pubmed/24860341 http://dx.doi.org/10.1107/S1600536814007442 |
Sumario: | The title compound, C(8)H(10)N(2)S, was prepared by reaction of methylamine solution, KOH and phenyl-isothiocyanate in ethanol. It adopts a syn-Me and anti-Ph conformation relative to the C=S double bond. The dihedral angle between the N—C(=S)—N thiourea and phenyl planes is 67.83 (6)°. In the crystal, the molecules centrosymmetrical dimers by pairs of N(Ph)—H⋯S hydrogen bonds. The dimers are linked by N(Me)—H⋯S hydrogen bonds into layers parallel to (100). |
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