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1-Methyl-3-phenyl­thio­urea

The title compound, C(8)H(10)N(2)S, was prepared by reaction of methyl­amine solution, KOH and phenyl-iso­thio­cyanate in ethanol. It adopts a syn-Me and anti-Ph conformation relative to the C=S double bond. The dihedral angle between the N—C(=S)—N thio­urea and phenyl planes is 67.83 (6)°. In the c...

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Detalles Bibliográficos
Autor principal: Su, Hou-xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011236/
https://www.ncbi.nlm.nih.gov/pubmed/24860341
http://dx.doi.org/10.1107/S1600536814007442
Descripción
Sumario:The title compound, C(8)H(10)N(2)S, was prepared by reaction of methyl­amine solution, KOH and phenyl-iso­thio­cyanate in ethanol. It adopts a syn-Me and anti-Ph conformation relative to the C=S double bond. The dihedral angle between the N—C(=S)—N thio­urea and phenyl planes is 67.83 (6)°. In the crystal, the mol­ecules centrosymmetrical dimers by pairs of N(Ph)—H⋯S hydrogen bonds. The dimers are linked by N(Me)—H⋯S hydrogen bonds into layers parallel to (100).