1-Methyl-3-phenyl­thio­urea

The title compound, C(8)H(10)N(2)S, was prepared by reaction of methyl­amine solution, KOH and phenyl-iso­thio­cyanate in ethanol. It adopts a syn-Me and anti-Ph conformation relative to the C=S double bond. The dihedral angle between the N—C(=S)—N thio­urea and phenyl planes is 67.83 (6)°. In the c...

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Autor principal: Su, Hou-xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011236/
https://www.ncbi.nlm.nih.gov/pubmed/24860341
http://dx.doi.org/10.1107/S1600536814007442
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author Su, Hou-xiang
author_facet Su, Hou-xiang
author_sort Su, Hou-xiang
collection PubMed
description The title compound, C(8)H(10)N(2)S, was prepared by reaction of methyl­amine solution, KOH and phenyl-iso­thio­cyanate in ethanol. It adopts a syn-Me and anti-Ph conformation relative to the C=S double bond. The dihedral angle between the N—C(=S)—N thio­urea and phenyl planes is 67.83 (6)°. In the crystal, the mol­ecules centrosymmetrical dimers by pairs of N(Ph)—H⋯S hydrogen bonds. The dimers are linked by N(Me)—H⋯S hydrogen bonds into layers parallel to (100).
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spelling pubmed-40112362014-05-23 1-Methyl-3-phenyl­thio­urea Su, Hou-xiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(10)N(2)S, was prepared by reaction of methyl­amine solution, KOH and phenyl-iso­thio­cyanate in ethanol. It adopts a syn-Me and anti-Ph conformation relative to the C=S double bond. The dihedral angle between the N—C(=S)—N thio­urea and phenyl planes is 67.83 (6)°. In the crystal, the mol­ecules centrosymmetrical dimers by pairs of N(Ph)—H⋯S hydrogen bonds. The dimers are linked by N(Me)—H⋯S hydrogen bonds into layers parallel to (100). International Union of Crystallography 2014-04-09 /pmc/articles/PMC4011236/ /pubmed/24860341 http://dx.doi.org/10.1107/S1600536814007442 Text en © Hou-xiang Su 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Su, Hou-xiang
1-Methyl-3-phenyl­thio­urea
title 1-Methyl-3-phenyl­thio­urea
title_full 1-Methyl-3-phenyl­thio­urea
title_fullStr 1-Methyl-3-phenyl­thio­urea
title_full_unstemmed 1-Methyl-3-phenyl­thio­urea
title_short 1-Methyl-3-phenyl­thio­urea
title_sort 1-methyl-3-phenyl­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011236/
https://www.ncbi.nlm.nih.gov/pubmed/24860341
http://dx.doi.org/10.1107/S1600536814007442
work_keys_str_mv AT suhouxiang 1methyl3phenylthiourea

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