1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate

In the title hydrated double salt, 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium hexa­aqua­iron(II) bis­(sulfate) monohydrate, (C(12)H(12)N(2))[Fe(H(2)O)(6)](SO(4))(2)·H(2)O, the Fe(II) cation is coordin­ated by six water mol­ecules in a slightly distorted octa­hedral geometry; the two pyridine rings of th...

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Detalles Bibliográficos
Autores principales: Yang, Dan, Yang, Fei-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011237/
https://www.ncbi.nlm.nih.gov/pubmed/24860304
http://dx.doi.org/10.1107/S1600536814007053
Descripción
Sumario:In the title hydrated double salt, 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium hexa­aqua­iron(II) bis­(sulfate) monohydrate, (C(12)H(12)N(2))[Fe(H(2)O)(6)](SO(4))(2)·H(2)O, the Fe(II) cation is coordin­ated by six water mol­ecules in a slightly distorted octa­hedral geometry; the two pyridine rings of the 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium cation are twisted to each other by a dihedral angle of 11.84 (10)°. In the crystal, the cations, sulfate anions and water mol­ecules of crystallization are linked by O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network.

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