1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate

In the title hydrated double salt, 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium hexa­aqua­iron(II) bis­(sulfate) monohydrate, (C(12)H(12)N(2))[Fe(H(2)O)(6)](SO(4))(2)·H(2)O, the Fe(II) cation is coordin­ated by six water mol­ecules in a slightly distorted octa­hedral geometry; the two pyridine rings of th...

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Detalles Bibliográficos
Autores principales: Yang, Dan, Yang, Fei-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011237/
https://www.ncbi.nlm.nih.gov/pubmed/24860304
http://dx.doi.org/10.1107/S1600536814007053
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author Yang, Dan
Yang, Fei-Lin
author_facet Yang, Dan
Yang, Fei-Lin
author_sort Yang, Dan
collection PubMed
description In the title hydrated double salt, 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium hexa­aqua­iron(II) bis­(sulfate) monohydrate, (C(12)H(12)N(2))[Fe(H(2)O)(6)](SO(4))(2)·H(2)O, the Fe(II) cation is coordin­ated by six water mol­ecules in a slightly distorted octa­hedral geometry; the two pyridine rings of the 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium cation are twisted to each other by a dihedral angle of 11.84 (10)°. In the crystal, the cations, sulfate anions and water mol­ecules of crystallization are linked by O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network.
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spelling pubmed-40112372014-05-23 1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate Yang, Dan Yang, Fei-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrated double salt, 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium hexa­aqua­iron(II) bis­(sulfate) monohydrate, (C(12)H(12)N(2))[Fe(H(2)O)(6)](SO(4))(2)·H(2)O, the Fe(II) cation is coordin­ated by six water mol­ecules in a slightly distorted octa­hedral geometry; the two pyridine rings of the 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium cation are twisted to each other by a dihedral angle of 11.84 (10)°. In the crystal, the cations, sulfate anions and water mol­ecules of crystallization are linked by O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. International Union of Crystallography 2014-04-05 /pmc/articles/PMC4011237/ /pubmed/24860304 http://dx.doi.org/10.1107/S1600536814007053 Text en © Yang and Yang 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Dan
Yang, Fei-Lin
1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate
title 1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate
title_full 1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate
title_fullStr 1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate
title_full_unstemmed 1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate
title_short 1:1 Co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(II) sulfate monohydrate
title_sort 1:1 co-crystal of 4,4′-(ethene-1,2-di­yl)dipyridin-1-ium sulfate and hexa­aqua­iron(ii) sulfate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011237/
https://www.ncbi.nlm.nih.gov/pubmed/24860304
http://dx.doi.org/10.1107/S1600536814007053
work_keys_str_mv AT yangdan 11cocrystalof44ethene12diyldipyridin1iumsulfateandhexaaquaironiisulfatemonohydrate
AT yangfeilin 11cocrystalof44ethene12diyldipyridin1iumsulfateandhexaaquaironiisulfatemonohydrate

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