Cargando…
2,8,15,18,21,24,31,37,44,47,50,53-Dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate
In the title compound, C(46)H(50)O(12)·2CH(2)Cl(2), each dual 20-crown-6 unit crystallizes with two dichloromethane solvent molecules. The crown unit molecule lies about an inversion centre located at the central benzene ring. The two crown ring groups adopt an anti conformation, stabilized by w...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011239/ https://www.ncbi.nlm.nih.gov/pubmed/24860365 http://dx.doi.org/10.1107/S1600536814007971 |
| _version_ | 1782314778201423872 |
|---|---|
| author | Yun, Ji Ye Ahn, Sung Wan Kim, Dong Hwan Sim, Wonbo Lee, Jai Young |
| author_facet | Yun, Ji Ye Ahn, Sung Wan Kim, Dong Hwan Sim, Wonbo Lee, Jai Young |
| author_sort | Yun, Ji Ye |
| collection | PubMed |
| description | In the title compound, C(46)H(50)O(12)·2CH(2)Cl(2), each dual 20-crown-6 unit crystallizes with two dichloromethane solvent molecules. The crown unit molecule lies about an inversion centre located at the central benzene ring. The two crown ring groups adopt an anti conformation, stabilized by weak intramolecular C—H⋯O interactions. In the crystal, the crown unit molecules and the solvent molecules are linked by C—H⋯O interactions into a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-4011239 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40112392014-05-23 2,8,15,18,21,24,31,37,44,47,50,53-Dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate Yun, Ji Ye Ahn, Sung Wan Kim, Dong Hwan Sim, Wonbo Lee, Jai Young Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(46)H(50)O(12)·2CH(2)Cl(2), each dual 20-crown-6 unit crystallizes with two dichloromethane solvent molecules. The crown unit molecule lies about an inversion centre located at the central benzene ring. The two crown ring groups adopt an anti conformation, stabilized by weak intramolecular C—H⋯O interactions. In the crystal, the crown unit molecules and the solvent molecules are linked by C—H⋯O interactions into a three-dimensional network. International Union of Crystallography 2014-04-16 /pmc/articles/PMC4011239/ /pubmed/24860365 http://dx.doi.org/10.1107/S1600536814007971 Text en © Yun et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Yun, Ji Ye Ahn, Sung Wan Kim, Dong Hwan Sim, Wonbo Lee, Jai Young 2,8,15,18,21,24,31,37,44,47,50,53-Dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate |
| title | 2,8,15,18,21,24,31,37,44,47,50,53-Dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate |
| title_full | 2,8,15,18,21,24,31,37,44,47,50,53-Dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate |
| title_fullStr | 2,8,15,18,21,24,31,37,44,47,50,53-Dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate |
| title_full_unstemmed | 2,8,15,18,21,24,31,37,44,47,50,53-Dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate |
| title_short | 2,8,15,18,21,24,31,37,44,47,50,53-Dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate |
| title_sort | 2,8,15,18,21,24,31,37,44,47,50,53-dodecaoxaheptacyclo[52.4.0.0(4,35).0(6,33).0(9,14).0(25,30).0(38,43)]octapentaconta-1(54),4,6(33),9(14),10,12,25(30),26,28,34,38(43),39,41,55,57-pentadecaene dichloromethane disolvate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011239/ https://www.ncbi.nlm.nih.gov/pubmed/24860365 http://dx.doi.org/10.1107/S1600536814007971 |
| work_keys_str_mv | AT yunjiye 2815182124313744475053dodecaoxaheptacyclo52400435063309140253003843octapentaconta154463391410122530262834384339415557pentadecaenedichloromethanedisolvate AT ahnsungwan 2815182124313744475053dodecaoxaheptacyclo52400435063309140253003843octapentaconta154463391410122530262834384339415557pentadecaenedichloromethanedisolvate AT kimdonghwan 2815182124313744475053dodecaoxaheptacyclo52400435063309140253003843octapentaconta154463391410122530262834384339415557pentadecaenedichloromethanedisolvate AT simwonbo 2815182124313744475053dodecaoxaheptacyclo52400435063309140253003843octapentaconta154463391410122530262834384339415557pentadecaenedichloromethanedisolvate AT leejaiyoung 2815182124313744475053dodecaoxaheptacyclo52400435063309140253003843octapentaconta154463391410122530262834384339415557pentadecaenedichloromethanedisolvate |