Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N (1),S)nickel(II)

In the title compound, [Ni(C(15)H(14)N(3)O(2)S)(2)], the Ni(II) atom lies on a center of symmetry. The deprotonated ligands act as N,S-donors, forming five-membered metalla-rings. The Ni(II) atom is four-coordinated in a slightly distorted square-planar environment. In the crystal, the discrete comp...

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Detalles Bibliográficos
Autores principales: de Oliveira, Adriano Bof, Feitosa, Bárbara Regina Santos, Näther, Christian, Jess, Inke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011249/
https://www.ncbi.nlm.nih.gov/pubmed/24860322
http://dx.doi.org/10.1107/S1600536814009027
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author de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_facet de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_sort de Oliveira, Adriano Bof
collection PubMed
description In the title compound, [Ni(C(15)H(14)N(3)O(2)S)(2)], the Ni(II) atom lies on a center of symmetry. The deprotonated ligands act as N,S-donors, forming five-membered metalla-rings. The Ni(II) atom is four-coordinated in a slightly distorted square-planar environment. In the crystal, the discrete complex mol­ecules are linked by weak N—H⋯O hydrogen bonds, generating chains along [110]. The chains are further connected via weak O—H⋯N inter­actions into a layered network extending parallel to (001).
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spelling pubmed-40112492014-05-23 Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N (1),S)nickel(II) de Oliveira, Adriano Bof Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(15)H(14)N(3)O(2)S)(2)], the Ni(II) atom lies on a center of symmetry. The deprotonated ligands act as N,S-donors, forming five-membered metalla-rings. The Ni(II) atom is four-coordinated in a slightly distorted square-planar environment. In the crystal, the discrete complex mol­ecules are linked by weak N—H⋯O hydrogen bonds, generating chains along [110]. The chains are further connected via weak O—H⋯N inter­actions into a layered network extending parallel to (001). International Union of Crystallography 2014-04-30 /pmc/articles/PMC4011249/ /pubmed/24860322 http://dx.doi.org/10.1107/S1600536814009027 Text en © Oliveira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N (1),S)nickel(II)
title Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N (1),S)nickel(II)
title_full Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N (1),S)nickel(II)
title_fullStr Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N (1),S)nickel(II)
title_full_unstemmed Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N (1),S)nickel(II)
title_short Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N (1),S)nickel(II)
title_sort bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-n (1),s)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011249/
https://www.ncbi.nlm.nih.gov/pubmed/24860322
http://dx.doi.org/10.1107/S1600536814009027
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AT natherchristian bis4hydroxy3methoxybenzaldehyde4phenylthiosemicarbazonaton1snickelii
AT jessinke bis4hydroxy3methoxybenzaldehyde4phenylthiosemicarbazonaton1snickelii

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