Bis[μ-1,3-bis­(1H-imidazol-1-yl)propane-κ(2) N (3):N (3′)]bis­(di­chlorido­zinc) dihydrate

The title hydrated complex, [Zn(2)Cl(4)(C(9)H(12)N(4))(2)]·2H(2)O, is a discrete dinuclear zinc complex with 1,3-bis­(1H-imidazol-1-yl)propane as the bridging ligand. The complex mol­ecule lies about a crystallographic inversion centre. The Zn(II) atom exhibits a distorted tetra­hedral coordination...

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Detalles Bibliográficos
Autores principales: Wang, Xiao-Juan, Feng, Yun-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011251/
https://www.ncbi.nlm.nih.gov/pubmed/24860315
http://dx.doi.org/10.1107/S1600536814008162
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author Wang, Xiao-Juan
Feng, Yun-Long
author_facet Wang, Xiao-Juan
Feng, Yun-Long
author_sort Wang, Xiao-Juan
collection PubMed
description The title hydrated complex, [Zn(2)Cl(4)(C(9)H(12)N(4))(2)]·2H(2)O, is a discrete dinuclear zinc complex with 1,3-bis­(1H-imidazol-1-yl)propane as the bridging ligand. The complex mol­ecule lies about a crystallographic inversion centre. The Zn(II) atom exhibits a distorted tetra­hedral coordination geometry defined by two imidazole N atoms and two Cl atoms. O—H⋯Cl hydrogen bonding between the lattice water mol­ecules and the terminal Cl atoms of the mol­ecule lead to a two-dimensional structure extending parallel to (100).
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spelling pubmed-40112512014-05-23 Bis[μ-1,3-bis­(1H-imidazol-1-yl)propane-κ(2) N (3):N (3′)]bis­(di­chlorido­zinc) dihydrate Wang, Xiao-Juan Feng, Yun-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title hydrated complex, [Zn(2)Cl(4)(C(9)H(12)N(4))(2)]·2H(2)O, is a discrete dinuclear zinc complex with 1,3-bis­(1H-imidazol-1-yl)propane as the bridging ligand. The complex mol­ecule lies about a crystallographic inversion centre. The Zn(II) atom exhibits a distorted tetra­hedral coordination geometry defined by two imidazole N atoms and two Cl atoms. O—H⋯Cl hydrogen bonding between the lattice water mol­ecules and the terminal Cl atoms of the mol­ecule lead to a two-dimensional structure extending parallel to (100). International Union of Crystallography 2014-04-16 /pmc/articles/PMC4011251/ /pubmed/24860315 http://dx.doi.org/10.1107/S1600536814008162 Text en © Wang and Feng 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xiao-Juan
Feng, Yun-Long
Bis[μ-1,3-bis­(1H-imidazol-1-yl)propane-κ(2) N (3):N (3′)]bis­(di­chlorido­zinc) dihydrate
title Bis[μ-1,3-bis­(1H-imidazol-1-yl)propane-κ(2) N (3):N (3′)]bis­(di­chlorido­zinc) dihydrate
title_full Bis[μ-1,3-bis­(1H-imidazol-1-yl)propane-κ(2) N (3):N (3′)]bis­(di­chlorido­zinc) dihydrate
title_fullStr Bis[μ-1,3-bis­(1H-imidazol-1-yl)propane-κ(2) N (3):N (3′)]bis­(di­chlorido­zinc) dihydrate
title_full_unstemmed Bis[μ-1,3-bis­(1H-imidazol-1-yl)propane-κ(2) N (3):N (3′)]bis­(di­chlorido­zinc) dihydrate
title_short Bis[μ-1,3-bis­(1H-imidazol-1-yl)propane-κ(2) N (3):N (3′)]bis­(di­chlorido­zinc) dihydrate
title_sort bis[μ-1,3-bis­(1h-imidazol-1-yl)propane-κ(2) n (3):n (3′)]bis­(di­chlorido­zinc) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011251/
https://www.ncbi.nlm.nih.gov/pubmed/24860315
http://dx.doi.org/10.1107/S1600536814008162
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