Bis{μ-cis-1,3-bis­[(di-tert-butyl­phosphan­yl)­oxy]cyclo­hexane-κ(2) P:P′}bis­[carbonylnickel(0)] including an unknown solvent molecule

The title compound, [Ni(2)(C(22)H(46)P(2)O(2))(2)(CO)(2)], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal–planar geometry. The cyclo­hexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific inter­molecula...

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Detalles Bibliográficos
Autores principales: Jonasson, Klara J., Wendt, Ola F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011252/
https://www.ncbi.nlm.nih.gov/pubmed/24860309
http://dx.doi.org/10.1107/S1600536814007818
Descripción
Sumario:The title compound, [Ni(2)(C(22)H(46)P(2)O(2))(2)(CO)(2)], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal–planar geometry. The cyclo­hexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific inter­molecular inter­actions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. Its formula mass and unit-cell characteristics were not taken into account during refinement.

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