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Bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2) P:P′}bis[carbonylnickel(0)] including an unknown solvent molecule
The title compound, [Ni(2)(C(22)H(46)P(2)O(2))(2)(CO)(2)], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal–planar geometry. The cyclohexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific intermolecula...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011252/ https://www.ncbi.nlm.nih.gov/pubmed/24860309 http://dx.doi.org/10.1107/S1600536814007818 |
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| author | Jonasson, Klara J. Wendt, Ola F. |
| author_facet | Jonasson, Klara J. Wendt, Ola F. |
| author_sort | Jonasson, Klara J. |
| collection | PubMed |
| description | The title compound, [Ni(2)(C(22)H(46)P(2)O(2))(2)(CO)(2)], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal–planar geometry. The cyclohexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific intermolecular interactions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. Its formula mass and unit-cell characteristics were not taken into account during refinement. |
| format | Online Article Text |
| id | pubmed-4011252 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40112522014-05-23 Bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2) P:P′}bis[carbonylnickel(0)] including an unknown solvent molecule Jonasson, Klara J. Wendt, Ola F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(2)(C(22)H(46)P(2)O(2))(2)(CO)(2)], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal–planar geometry. The cyclohexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific intermolecular interactions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. Its formula mass and unit-cell characteristics were not taken into account during refinement. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011252/ /pubmed/24860309 http://dx.doi.org/10.1107/S1600536814007818 Text en © Jonasson and Wendt 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jonasson, Klara J. Wendt, Ola F. Bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2) P:P′}bis[carbonylnickel(0)] including an unknown solvent molecule |
| title | Bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2)
P:P′}bis[carbonylnickel(0)] including an unknown solvent molecule |
| title_full | Bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2)
P:P′}bis[carbonylnickel(0)] including an unknown solvent molecule |
| title_fullStr | Bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2)
P:P′}bis[carbonylnickel(0)] including an unknown solvent molecule |
| title_full_unstemmed | Bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2)
P:P′}bis[carbonylnickel(0)] including an unknown solvent molecule |
| title_short | Bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2)
P:P′}bis[carbonylnickel(0)] including an unknown solvent molecule |
| title_sort | bis{μ-cis-1,3-bis[(di-tert-butylphosphanyl)oxy]cyclohexane-κ(2)
p:p′}bis[carbonylnickel(0)] including an unknown solvent molecule |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011252/ https://www.ncbi.nlm.nih.gov/pubmed/24860309 http://dx.doi.org/10.1107/S1600536814007818 |
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