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Piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3) O,O′,O′′)cobaltate(II) hexahydrate
In the title hydrate, (C(4)H(12)N(2))[Co{B(6)O(7)(OH)(6)}(2)]·6H(2)O, both the dication and dianion are generated by crystallographic inversion symmetry. The Co(2+) ion in the dianion adopts a fairly regular CoO(6) octahedral coordination geometry arising from the two O,O′,O′′-tridentate ligands. I...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011254/ https://www.ncbi.nlm.nih.gov/pubmed/24860303 http://dx.doi.org/10.1107/S1600536814007090 |
| _version_ | 1782314781724639232 |
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| author | Jamai, Nabil Rzaigui, Mohamed Toumi, Samah Akriche |
| author_facet | Jamai, Nabil Rzaigui, Mohamed Toumi, Samah Akriche |
| author_sort | Jamai, Nabil |
| collection | PubMed |
| description | In the title hydrate, (C(4)H(12)N(2))[Co{B(6)O(7)(OH)(6)}(2)]·6H(2)O, both the dication and dianion are generated by crystallographic inversion symmetry. The Co(2+) ion in the dianion adopts a fairly regular CoO(6) octahedral coordination geometry arising from the two O,O′,O′′-tridentate ligands. In the crystal, the dianions and water molecules are linked by O—H⋯O hydrogen bonds, generating a framework with large [100] channels, which are occupied by the organic dications. N—H⋯O and C—H⋯O hydrogen bonds consolidate the structure. |
| format | Online Article Text |
| id | pubmed-4011254 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40112542014-05-23 Piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3) O,O′,O′′)cobaltate(II) hexahydrate Jamai, Nabil Rzaigui, Mohamed Toumi, Samah Akriche Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrate, (C(4)H(12)N(2))[Co{B(6)O(7)(OH)(6)}(2)]·6H(2)O, both the dication and dianion are generated by crystallographic inversion symmetry. The Co(2+) ion in the dianion adopts a fairly regular CoO(6) octahedral coordination geometry arising from the two O,O′,O′′-tridentate ligands. In the crystal, the dianions and water molecules are linked by O—H⋯O hydrogen bonds, generating a framework with large [100] channels, which are occupied by the organic dications. N—H⋯O and C—H⋯O hydrogen bonds consolidate the structure. International Union of Crystallography 2014-04-05 /pmc/articles/PMC4011254/ /pubmed/24860303 http://dx.doi.org/10.1107/S1600536814007090 Text en © Jamai et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jamai, Nabil Rzaigui, Mohamed Toumi, Samah Akriche Piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3) O,O′,O′′)cobaltate(II) hexahydrate |
| title | Piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3)
O,O′,O′′)cobaltate(II) hexahydrate |
| title_full | Piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3)
O,O′,O′′)cobaltate(II) hexahydrate |
| title_fullStr | Piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3)
O,O′,O′′)cobaltate(II) hexahydrate |
| title_full_unstemmed | Piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3)
O,O′,O′′)cobaltate(II) hexahydrate |
| title_short | Piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3)
O,O′,O′′)cobaltate(II) hexahydrate |
| title_sort | piperazine-1,4-diium bis(hexahydroxidoheptaoxidohexaborato-κ(3)
o,o′,o′′)cobaltate(ii) hexahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011254/ https://www.ncbi.nlm.nih.gov/pubmed/24860303 http://dx.doi.org/10.1107/S1600536814007090 |
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