(3-Methyl-3a,4,7,7a-tetra­hydro-5H-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone

The title compound, C(14)H(14)N(2)O(3), is the exo isomer with a syn arrangement of two O atoms in the isoxazole and oxazine rings. The dihedral angle between the isoxazole and phenyl rings is 60.38 (4)°. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional netw...

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Detalles Bibliográficos
Autores principales: Lough, Alan J., Nagireddy, Jaipal R., Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011260/
https://www.ncbi.nlm.nih.gov/pubmed/24860351
http://dx.doi.org/10.1107/S1600536814007740
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author Lough, Alan J.
Nagireddy, Jaipal R.
Tam, William
author_facet Lough, Alan J.
Nagireddy, Jaipal R.
Tam, William
author_sort Lough, Alan J.
collection PubMed
description The title compound, C(14)H(14)N(2)O(3), is the exo isomer with a syn arrangement of two O atoms in the isoxazole and oxazine rings. The dihedral angle between the isoxazole and phenyl rings is 60.38 (4)°. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network. The isoxazole O atom is an acceptor for three of these hydrogen bonds.
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spelling pubmed-40112602014-05-23 (3-Methyl-3a,4,7,7a-tetra­hydro-5H-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone Lough, Alan J. Nagireddy, Jaipal R. Tam, William Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(14)N(2)O(3), is the exo isomer with a syn arrangement of two O atoms in the isoxazole and oxazine rings. The dihedral angle between the isoxazole and phenyl rings is 60.38 (4)°. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network. The isoxazole O atom is an acceptor for three of these hydrogen bonds. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011260/ /pubmed/24860351 http://dx.doi.org/10.1107/S1600536814007740 Text en © Lough et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lough, Alan J.
Nagireddy, Jaipal R.
Tam, William
(3-Methyl-3a,4,7,7a-tetra­hydro-5H-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone
title (3-Methyl-3a,4,7,7a-tetra­hydro-5H-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone
title_full (3-Methyl-3a,4,7,7a-tetra­hydro-5H-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone
title_fullStr (3-Methyl-3a,4,7,7a-tetra­hydro-5H-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone
title_full_unstemmed (3-Methyl-3a,4,7,7a-tetra­hydro-5H-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone
title_short (3-Methyl-3a,4,7,7a-tetra­hydro-5H-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone
title_sort (3-methyl-3a,4,7,7a-tetra­hydro-5h-4,7-methano­isoxazolo[4,5-d][1,2]oxazin-5-yl)(phen­yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011260/
https://www.ncbi.nlm.nih.gov/pubmed/24860351
http://dx.doi.org/10.1107/S1600536814007740
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AT tamwilliam 3methyl3a477atetrahydro5h47methanoisoxazolo45d12oxazin5ylphenylmethanone

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