(E)-3-Isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one O-nicotinoyl oxime

In the title compound, C(27)H(29)N(3)O(2), the piperidine ring exists in a chair conformation with an equatorial orientation of the phenyl and methyl substituents. The C—C=N bond angles are significantly different [119.1 (2) and 127.2 (2)°]. The phenyl rings are inclined to one another by 44.90 (14)...

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Autores principales: Vinuchakkaravarthy, T., Sivakumar, R., Srinivasan, T., Thanikachalam, V., Velmurugan, D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011261/
https://www.ncbi.nlm.nih.gov/pubmed/24860359
http://dx.doi.org/10.1107/S1600536814007363
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author Vinuchakkaravarthy, T.
Sivakumar, R.
Srinivasan, T.
Thanikachalam, V.
Velmurugan, D.
author_facet Vinuchakkaravarthy, T.
Sivakumar, R.
Srinivasan, T.
Thanikachalam, V.
Velmurugan, D.
author_sort Vinuchakkaravarthy, T.
collection PubMed
description In the title compound, C(27)H(29)N(3)O(2), the piperidine ring exists in a chair conformation with an equatorial orientation of the phenyl and methyl substituents. The C—C=N bond angles are significantly different [119.1 (2) and 127.2 (2)°]. The phenyl rings are inclined to one another by 44.90 (14)°, and by 80.85 (13) and 79.62 (12)° to the mean plane of the piperidine ring. The terminal pyridine ring is inclined to the piperidine ring mean plane by 74.79 (15)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming a three-dimensional network.
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spelling pubmed-40112612014-05-23 (E)-3-Isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one O-nicotinoyl oxime Vinuchakkaravarthy, T. Sivakumar, R. Srinivasan, T. Thanikachalam, V. Velmurugan, D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(29)N(3)O(2), the piperidine ring exists in a chair conformation with an equatorial orientation of the phenyl and methyl substituents. The C—C=N bond angles are significantly different [119.1 (2) and 127.2 (2)°]. The phenyl rings are inclined to one another by 44.90 (14)°, and by 80.85 (13) and 79.62 (12)° to the mean plane of the piperidine ring. The terminal pyridine ring is inclined to the piperidine ring mean plane by 74.79 (15)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming a three-dimensional network. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011261/ /pubmed/24860359 http://dx.doi.org/10.1107/S1600536814007363 Text en © Vinuchakkaravarthy et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vinuchakkaravarthy, T.
Sivakumar, R.
Srinivasan, T.
Thanikachalam, V.
Velmurugan, D.
(E)-3-Isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one O-nicotinoyl oxime
title (E)-3-Isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one O-nicotinoyl oxime
title_full (E)-3-Isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one O-nicotinoyl oxime
title_fullStr (E)-3-Isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one O-nicotinoyl oxime
title_full_unstemmed (E)-3-Isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one O-nicotinoyl oxime
title_short (E)-3-Isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one O-nicotinoyl oxime
title_sort (e)-3-isopropyl-1-methyl-2,6-di­phenyl­piperidin-4-one o-nicotinoyl oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011261/
https://www.ncbi.nlm.nih.gov/pubmed/24860359
http://dx.doi.org/10.1107/S1600536814007363
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