Cargando…

3-Bromo-2-[4-(methyl­sulfan­yl)phen­yl]-5,6,7,8-tetra­hydro-1,3-benzo­thia­zolo[3,2-a]imidazole

In the title mol­ecule, C(16)H(15)BrN(2)S(2), the central imidazo[2,1-b]thia­zole fragment is almost planar (r.m.s. deviation = 0.012 Å), and the fused 5,6,7,8-tetra­hydro­benzene ring adopts an unsymmetrical half-chair conformation. The dihedral angle between the imidazo[2,1-b]thia­zole and benzene...

Descripción completa

Detalles Bibliográficos
Autores principales: Bunev, Alexander S., Sukhonosova, Elena V., Statsyuk, Vladimir E., Ostapenko, Gennady I., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011264/
https://www.ncbi.nlm.nih.gov/pubmed/24860393
http://dx.doi.org/10.1107/S1600536814008976
Descripción
Sumario:In the title mol­ecule, C(16)H(15)BrN(2)S(2), the central imidazo[2,1-b]thia­zole fragment is almost planar (r.m.s. deviation = 0.012 Å), and the fused 5,6,7,8-tetra­hydro­benzene ring adopts an unsymmetrical half-chair conformation. The dihedral angle between the imidazo[2,1-b]thia­zole and benzene planes is 18.25 (4)°. The terminal methyl­sulfanyl substituent lies practically within the benzene plane [the dihedral angle between the corresponding planes is 7.20 (10)°] and is turned toward the C—Br bond. In the crystal, mol­ecules form infinite chains along [100] via secondary Br⋯N inter­actions [3.1861 (16) Å]. The chains are arranged at van der Waals distances.