Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)]

In the title tetra­nuclear compound, [Cu(4)(C(7)H(14)NO)(4)Cl(4)], each Cu(II) cation is N,O-chelated by a piperidineethanolate anion and coordinated by a Cl(−) anion and two O atoms from neighboring piperidine­ethano­late anions in a distorted NO(3)Cl square-pyramidal geometry. The deprotonated hyd...

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Detalles Bibliográficos
Autores principales: Luo, Mei, Huang, Yong-Hua, Zhang, Jing-Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011270/
https://www.ncbi.nlm.nih.gov/pubmed/24860321
http://dx.doi.org/10.1107/S1600536814009052
Descripción
Sumario:In the title tetra­nuclear compound, [Cu(4)(C(7)H(14)NO)(4)Cl(4)], each Cu(II) cation is N,O-chelated by a piperidineethanolate anion and coordinated by a Cl(−) anion and two O atoms from neighboring piperidine­ethano­late anions in a distorted NO(3)Cl square-pyramidal geometry. The deprotonated hydroxyl groups of the piperidineethanolate anions bridge Cu(II) cations, forming the tetra­nuclear complex. All piperidine rings display a chair conformation. In the crystal, there are no significant inter­molecular inter­actions present. The crystal studied was an inversion twin refined with a minor component of 0.18 (5).

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