Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)]

In the title tetra­nuclear compound, [Cu(4)(C(7)H(14)NO)(4)Cl(4)], each Cu(II) cation is N,O-chelated by a piperidineethanolate anion and coordinated by a Cl(−) anion and two O atoms from neighboring piperidine­ethano­late anions in a distorted NO(3)Cl square-pyramidal geometry. The deprotonated hyd...

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Detalles Bibliográficos
Autores principales: Luo, Mei, Huang, Yong-Hua, Zhang, Jing-Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011270/
https://www.ncbi.nlm.nih.gov/pubmed/24860321
http://dx.doi.org/10.1107/S1600536814009052
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author Luo, Mei
Huang, Yong-Hua
Zhang, Jing-Cheng
author_facet Luo, Mei
Huang, Yong-Hua
Zhang, Jing-Cheng
author_sort Luo, Mei
collection PubMed
description In the title tetra­nuclear compound, [Cu(4)(C(7)H(14)NO)(4)Cl(4)], each Cu(II) cation is N,O-chelated by a piperidineethanolate anion and coordinated by a Cl(−) anion and two O atoms from neighboring piperidine­ethano­late anions in a distorted NO(3)Cl square-pyramidal geometry. The deprotonated hydroxyl groups of the piperidineethanolate anions bridge Cu(II) cations, forming the tetra­nuclear complex. All piperidine rings display a chair conformation. In the crystal, there are no significant inter­molecular inter­actions present. The crystal studied was an inversion twin refined with a minor component of 0.18 (5).
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spelling pubmed-40112702014-05-23 Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)] Luo, Mei Huang, Yong-Hua Zhang, Jing-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title tetra­nuclear compound, [Cu(4)(C(7)H(14)NO)(4)Cl(4)], each Cu(II) cation is N,O-chelated by a piperidineethanolate anion and coordinated by a Cl(−) anion and two O atoms from neighboring piperidine­ethano­late anions in a distorted NO(3)Cl square-pyramidal geometry. The deprotonated hydroxyl groups of the piperidineethanolate anions bridge Cu(II) cations, forming the tetra­nuclear complex. All piperidine rings display a chair conformation. In the crystal, there are no significant inter­molecular inter­actions present. The crystal studied was an inversion twin refined with a minor component of 0.18 (5). International Union of Crystallography 2014-04-30 /pmc/articles/PMC4011270/ /pubmed/24860321 http://dx.doi.org/10.1107/S1600536814009052 Text en © Luo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Mei
Huang, Yong-Hua
Zhang, Jing-Cheng
Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)]
title Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)]
title_full Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)]
title_fullStr Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)]
title_full_unstemmed Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)]
title_short Tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(II)]
title_sort tetrakis[μ(3)-2-(piperidin-1-yl)ethanolato]tetrakis[chloridocopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011270/
https://www.ncbi.nlm.nih.gov/pubmed/24860321
http://dx.doi.org/10.1107/S1600536814009052
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AT zhangjingcheng tetrakism32piperidin1ylethanolatotetrakischloridocopperii

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