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A new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate

The title mol­ecule, [Cu(C(12)H(8)N(2))(2)(H(2)O)](NO(3))(2), is a new polymorph of a compound which up to now has been reported to crystallize space groups in C2/c and Cc. The crystal studied was twinned by non-merohedry (final BASF factor of 0.40043) with the structure being solved and refined in...

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Autores principales: Boutebdja, Mehdi, Lehleh, Asma, Beghidja, Adel, Setifi, Zouaoui, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011280/
https://www.ncbi.nlm.nih.gov/pubmed/24860316
http://dx.doi.org/10.1107/S1600536814008198
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author Boutebdja, Mehdi
Lehleh, Asma
Beghidja, Adel
Setifi, Zouaoui
Merazig, Hocine
author_facet Boutebdja, Mehdi
Lehleh, Asma
Beghidja, Adel
Setifi, Zouaoui
Merazig, Hocine
author_sort Boutebdja, Mehdi
collection PubMed
description The title mol­ecule, [Cu(C(12)H(8)N(2))(2)(H(2)O)](NO(3))(2), is a new polymorph of a compound which up to now has been reported to crystallize space groups in C2/c and Cc. The crystal studied was twinned by non-merohedry (final BASF factor of 0.40043) with the structure being solved and refined in P-1. The Cu(II) atom is coordinated by four N atoms from two 1,10-phenanthroline ligands and an O atom from a water mol­ecule in an approximate trigonal–bipyramidal geometry. Discrete entities of one cation and two nitrate anions are formed by water–nitrate O—H⋯O hydrogen bonds. The components are further assembled into a three-dimensional network by C—H⋯O hydrogen bonds.
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spelling pubmed-40112802014-05-23 A new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate Boutebdja, Mehdi Lehleh, Asma Beghidja, Adel Setifi, Zouaoui Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mol­ecule, [Cu(C(12)H(8)N(2))(2)(H(2)O)](NO(3))(2), is a new polymorph of a compound which up to now has been reported to crystallize space groups in C2/c and Cc. The crystal studied was twinned by non-merohedry (final BASF factor of 0.40043) with the structure being solved and refined in P-1. The Cu(II) atom is coordinated by four N atoms from two 1,10-phenanthroline ligands and an O atom from a water mol­ecule in an approximate trigonal–bipyramidal geometry. Discrete entities of one cation and two nitrate anions are formed by water–nitrate O—H⋯O hydrogen bonds. The components are further assembled into a three-dimensional network by C—H⋯O hydrogen bonds. International Union of Crystallography 2014-04-18 /pmc/articles/PMC4011280/ /pubmed/24860316 http://dx.doi.org/10.1107/S1600536814008198 Text en © Boutebdja et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boutebdja, Mehdi
Lehleh, Asma
Beghidja, Adel
Setifi, Zouaoui
Merazig, Hocine
A new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate
title A new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate
title_full A new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate
title_fullStr A new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate
title_full_unstemmed A new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate
title_short A new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate
title_sort new polymorph of aqua­bis­(1,10-phenanthroline-κ(2) n,n′)copper(ii) dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011280/
https://www.ncbi.nlm.nih.gov/pubmed/24860316
http://dx.doi.org/10.1107/S1600536814008198
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