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A new polymorph of aquabis(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate
The title molecule, [Cu(C(12)H(8)N(2))(2)(H(2)O)](NO(3))(2), is a new polymorph of a compound which up to now has been reported to crystallize space groups in C2/c and Cc. The crystal studied was twinned by non-merohedry (final BASF factor of 0.40043) with the structure being solved and refined in...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011280/ https://www.ncbi.nlm.nih.gov/pubmed/24860316 http://dx.doi.org/10.1107/S1600536814008198 |
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author | Boutebdja, Mehdi Lehleh, Asma Beghidja, Adel Setifi, Zouaoui Merazig, Hocine |
author_facet | Boutebdja, Mehdi Lehleh, Asma Beghidja, Adel Setifi, Zouaoui Merazig, Hocine |
author_sort | Boutebdja, Mehdi |
collection | PubMed |
description | The title molecule, [Cu(C(12)H(8)N(2))(2)(H(2)O)](NO(3))(2), is a new polymorph of a compound which up to now has been reported to crystallize space groups in C2/c and Cc. The crystal studied was twinned by non-merohedry (final BASF factor of 0.40043) with the structure being solved and refined in P-1. The Cu(II) atom is coordinated by four N atoms from two 1,10-phenanthroline ligands and an O atom from a water molecule in an approximate trigonal–bipyramidal geometry. Discrete entities of one cation and two nitrate anions are formed by water–nitrate O—H⋯O hydrogen bonds. The components are further assembled into a three-dimensional network by C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-4011280 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40112802014-05-23 A new polymorph of aquabis(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate Boutebdja, Mehdi Lehleh, Asma Beghidja, Adel Setifi, Zouaoui Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title molecule, [Cu(C(12)H(8)N(2))(2)(H(2)O)](NO(3))(2), is a new polymorph of a compound which up to now has been reported to crystallize space groups in C2/c and Cc. The crystal studied was twinned by non-merohedry (final BASF factor of 0.40043) with the structure being solved and refined in P-1. The Cu(II) atom is coordinated by four N atoms from two 1,10-phenanthroline ligands and an O atom from a water molecule in an approximate trigonal–bipyramidal geometry. Discrete entities of one cation and two nitrate anions are formed by water–nitrate O—H⋯O hydrogen bonds. The components are further assembled into a three-dimensional network by C—H⋯O hydrogen bonds. International Union of Crystallography 2014-04-18 /pmc/articles/PMC4011280/ /pubmed/24860316 http://dx.doi.org/10.1107/S1600536814008198 Text en © Boutebdja et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Boutebdja, Mehdi Lehleh, Asma Beghidja, Adel Setifi, Zouaoui Merazig, Hocine A new polymorph of aquabis(1,10-phenanthroline-κ(2) N,N′)copper(II) dinitrate |
title | A new polymorph of aquabis(1,10-phenanthroline-κ(2)
N,N′)copper(II) dinitrate |
title_full | A new polymorph of aquabis(1,10-phenanthroline-κ(2)
N,N′)copper(II) dinitrate |
title_fullStr | A new polymorph of aquabis(1,10-phenanthroline-κ(2)
N,N′)copper(II) dinitrate |
title_full_unstemmed | A new polymorph of aquabis(1,10-phenanthroline-κ(2)
N,N′)copper(II) dinitrate |
title_short | A new polymorph of aquabis(1,10-phenanthroline-κ(2)
N,N′)copper(II) dinitrate |
title_sort | new polymorph of aquabis(1,10-phenanthroline-κ(2)
n,n′)copper(ii) dinitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011280/ https://www.ncbi.nlm.nih.gov/pubmed/24860316 http://dx.doi.org/10.1107/S1600536814008198 |
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