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{[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene

The title compound, C(23)H(24)O(3), was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C—C bond and the phenoxy substituents i...

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Detalles Bibliográficos
Autores principales: Moussa, Ziad, Al-Masri, Harbi Tomah, Shraim, Amjed, Fettouhi, Mohammed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011283/
https://www.ncbi.nlm.nih.gov/pubmed/24860348
http://dx.doi.org/10.1107/S1600536814007594
Descripción
Sumario:The title compound, C(23)H(24)O(3), was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C—C bond and the phenoxy substituents is antiperiplanar while the two others are synclinal [the corresponding C—C—C—O torsion angles are −174.6 (1), −53.2 (2) and −47.3 (2)°]. In the crystal, C—H⋯O inter­actions link the molecules into [010] chains.