{[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene

The title compound, C(23)H(24)O(3), was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C—C bond and the phenoxy substituents i...

Descripción completa

Detalles Bibliográficos
Autores principales: Moussa, Ziad, Al-Masri, Harbi Tomah, Shraim, Amjed, Fettouhi, Mohammed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011283/
https://www.ncbi.nlm.nih.gov/pubmed/24860348
http://dx.doi.org/10.1107/S1600536814007594
_version_ 1782314788403019776
author Moussa, Ziad
Al-Masri, Harbi Tomah
Shraim, Amjed
Fettouhi, Mohammed
author_facet Moussa, Ziad
Al-Masri, Harbi Tomah
Shraim, Amjed
Fettouhi, Mohammed
author_sort Moussa, Ziad
collection PubMed
description The title compound, C(23)H(24)O(3), was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C—C bond and the phenoxy substituents is antiperiplanar while the two others are synclinal [the corresponding C—C—C—O torsion angles are −174.6 (1), −53.2 (2) and −47.3 (2)°]. In the crystal, C—H⋯O inter­actions link the molecules into [010] chains.
format Online
Article
Text
id pubmed-4011283
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-40112832014-05-23 {[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene Moussa, Ziad Al-Masri, Harbi Tomah Shraim, Amjed Fettouhi, Mohammed Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(24)O(3), was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C—C bond and the phenoxy substituents is antiperiplanar while the two others are synclinal [the corresponding C—C—C—O torsion angles are −174.6 (1), −53.2 (2) and −47.3 (2)°]. In the crystal, C—H⋯O inter­actions link the molecules into [010] chains. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011283/ /pubmed/24860348 http://dx.doi.org/10.1107/S1600536814007594 Text en © Moussa et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moussa, Ziad
Al-Masri, Harbi Tomah
Shraim, Amjed
Fettouhi, Mohammed
{[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene
title {[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene
title_full {[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene
title_fullStr {[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene
title_full_unstemmed {[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene
title_short {[2-Methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene
title_sort {[2-methyl-2-(phen­oxy­meth­yl)propane-1,3-di­yl]bis­(­oxy)}di­benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011283/
https://www.ncbi.nlm.nih.gov/pubmed/24860348
http://dx.doi.org/10.1107/S1600536814007594
work_keys_str_mv AT moussaziad 2methyl2phenoxymethylpropane13diylbisoxydibenzene
AT almasriharbitomah 2methyl2phenoxymethylpropane13diylbisoxydibenzene
AT shraimamjed 2methyl2phenoxymethylpropane13diylbisoxydibenzene
AT fettouhimohammed 2methyl2phenoxymethylpropane13diylbisoxydibenzene

Ejemplares similares