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(1E,4E)-1,5-Bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one

There are two crystallograpically independent mol­ecules in the asymmetric unit of the title bis­chalcone derivative, C(25)H(32)N(2)O. Both mol­ecules are twisted with a dihedral angle between the two substituted benzene rings of 11.19 (16)° in one mol­ecule and 14.40 (15)° in the other. The central...

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Autores principales: Ruanwas, Pumsak, Chantrapromma, Suchada, Ghabbour, Hazem A., Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011286/
https://www.ncbi.nlm.nih.gov/pubmed/24860388
http://dx.doi.org/10.1107/S1600536814008356
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author Ruanwas, Pumsak
Chantrapromma, Suchada
Ghabbour, Hazem A.
Fun, Hoong-Kun
author_facet Ruanwas, Pumsak
Chantrapromma, Suchada
Ghabbour, Hazem A.
Fun, Hoong-Kun
author_sort Ruanwas, Pumsak
collection PubMed
description There are two crystallograpically independent mol­ecules in the asymmetric unit of the title bis­chalcone derivative, C(25)H(32)N(2)O. Both mol­ecules are twisted with a dihedral angle between the two substituted benzene rings of 11.19 (16)° in one mol­ecule and 14.40 (15)° in the other. The central penta-1,4-dien-3-one fragments make dihedral angles of 8.49 (17) and 4.26 (17)° with the two adjacent benzene rings in one mol­ecule, whereas the corresponding values are 8.42 (16) and 6.18 (16)° in the other. In the crystal, mol­ecules are arranged into chains along the c-axis direction. Adjacent chains are inter-linked by weak inter­molecular C—H⋯O inter­actions. The crystal is further stabilized by C—H⋯π inter­actions.
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spelling pubmed-40112862014-05-23 (1E,4E)-1,5-Bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one Ruanwas, Pumsak Chantrapromma, Suchada Ghabbour, Hazem A. Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two crystallograpically independent mol­ecules in the asymmetric unit of the title bis­chalcone derivative, C(25)H(32)N(2)O. Both mol­ecules are twisted with a dihedral angle between the two substituted benzene rings of 11.19 (16)° in one mol­ecule and 14.40 (15)° in the other. The central penta-1,4-dien-3-one fragments make dihedral angles of 8.49 (17) and 4.26 (17)° with the two adjacent benzene rings in one mol­ecule, whereas the corresponding values are 8.42 (16) and 6.18 (16)° in the other. In the crystal, mol­ecules are arranged into chains along the c-axis direction. Adjacent chains are inter-linked by weak inter­molecular C—H⋯O inter­actions. The crystal is further stabilized by C—H⋯π inter­actions. International Union of Crystallography 2014-04-26 /pmc/articles/PMC4011286/ /pubmed/24860388 http://dx.doi.org/10.1107/S1600536814008356 Text en © Ruanwas et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ruanwas, Pumsak
Chantrapromma, Suchada
Ghabbour, Hazem A.
Fun, Hoong-Kun
(1E,4E)-1,5-Bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one
title (1E,4E)-1,5-Bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one
title_full (1E,4E)-1,5-Bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one
title_fullStr (1E,4E)-1,5-Bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one
title_full_unstemmed (1E,4E)-1,5-Bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one
title_short (1E,4E)-1,5-Bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one
title_sort (1e,4e)-1,5-bis[4-(di­ethyl­amino)­phen­yl]penta-1,4-dien-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011286/
https://www.ncbi.nlm.nih.gov/pubmed/24860388
http://dx.doi.org/10.1107/S1600536814008356
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