Poly[(μ(3)-3,5-diisopropyl-4H-1,2,4-triazolato-κ(3) N:N′:N′′)silver(I)]

In the polymeric title compound, [Ag(C(8)H(14)N(3))](n), the Ag(I) cation is coordinated by three N atoms from three 3,5-diisopropyl-1,2,4-triazolate anions in a T-shaped geometry. The Ag(I) cation deviates from the coordination plane by 0.014 (1) Å and the N—Ag—N bond angles are 96.85 (11), 97.72 (...

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Detalles Bibliográficos
Autores principales: Cui, Guo-Gen, Yang, Xiao-Xi, Yang, Jian-Ping, Jiang, Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011292/
https://www.ncbi.nlm.nih.gov/pubmed/24860318
http://dx.doi.org/10.1107/S1600536814008083
Descripción
Sumario:In the polymeric title compound, [Ag(C(8)H(14)N(3))](n), the Ag(I) cation is coordinated by three N atoms from three 3,5-diisopropyl-1,2,4-triazolate anions in a T-shaped geometry. The Ag(I) cation deviates from the coordination plane by 0.014 (1) Å and the N—Ag—N bond angles are 96.85 (11), 97.72 (10) and 165.39 (12)°. The triazolate anion bridges three Ag(I) cations, forming a three-dimensional polymeric network.

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