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Poly[(μ(4)-decanedioato)cobalt(II)]
In the title compound, [Co(C(10)H(16)O(4))](n), the Co(II) atom is bonded in a slightly distorted tetrahedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011297/ https://www.ncbi.nlm.nih.gov/pubmed/24860298 http://dx.doi.org/10.1107/S1600536814006011 |
Sumario: | In the title compound, [Co(C(10)H(16)O(4))](n), the Co(II) atom is bonded in a slightly distorted tetrahedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network coordination polymer, there are two different spatial extensions of Co(II) atoms, one with the Co(II) atoms lying parallel to (100) [Co⋯Co = 4.653 (1) Å], the other lying parallel to (010) [Co⋯Co = 4.764 (1) Å]. |
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