Poly[(μ(4)-decanedio­ato)cobalt(II)]

In the title compound, [Co(C(10)H(16)O(4))](n), the Co(II) atom is bonded in a slightly distorted tetra­hedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network...

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Autores principales: Giuseppe, Bruno, Francesco, Nicolò, Giovanni, Grassi, Alessandro, Saccà, Mollica Nardo, Viviana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011297/
https://www.ncbi.nlm.nih.gov/pubmed/24860298
http://dx.doi.org/10.1107/S1600536814006011
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author Giuseppe, Bruno
Francesco, Nicolò
Giovanni, Grassi
Alessandro, Saccà
Mollica Nardo, Viviana
author_facet Giuseppe, Bruno
Francesco, Nicolò
Giovanni, Grassi
Alessandro, Saccà
Mollica Nardo, Viviana
author_sort Giuseppe, Bruno
collection PubMed
description In the title compound, [Co(C(10)H(16)O(4))](n), the Co(II) atom is bonded in a slightly distorted tetra­hedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network coordination polymer, there are two different spatial extensions of Co(II) atoms, one with the Co(II) atoms lying parallel to (100) [Co⋯Co = 4.653 (1) Å], the other lying parallel to (010) [Co⋯Co = 4.764 (1) Å].
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spelling pubmed-40112972014-05-23 Poly[(μ(4)-decanedio­ato)cobalt(II)] Giuseppe, Bruno Francesco, Nicolò Giovanni, Grassi Alessandro, Saccà Mollica Nardo, Viviana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(10)H(16)O(4))](n), the Co(II) atom is bonded in a slightly distorted tetra­hedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network coordination polymer, there are two different spatial extensions of Co(II) atoms, one with the Co(II) atoms lying parallel to (100) [Co⋯Co = 4.653 (1) Å], the other lying parallel to (010) [Co⋯Co = 4.764 (1) Å]. International Union of Crystallography 2014-04-02 /pmc/articles/PMC4011297/ /pubmed/24860298 http://dx.doi.org/10.1107/S1600536814006011 Text en © Giuseppe et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Giuseppe, Bruno
Francesco, Nicolò
Giovanni, Grassi
Alessandro, Saccà
Mollica Nardo, Viviana
Poly[(μ(4)-decanedio­ato)cobalt(II)]
title Poly[(μ(4)-decanedio­ato)cobalt(II)]
title_full Poly[(μ(4)-decanedio­ato)cobalt(II)]
title_fullStr Poly[(μ(4)-decanedio­ato)cobalt(II)]
title_full_unstemmed Poly[(μ(4)-decanedio­ato)cobalt(II)]
title_short Poly[(μ(4)-decanedio­ato)cobalt(II)]
title_sort poly[(μ(4)-decanedio­ato)cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011297/
https://www.ncbi.nlm.nih.gov/pubmed/24860298
http://dx.doi.org/10.1107/S1600536814006011
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AT giovannigrassi polym4decanedioatocobaltii
AT alessandrosacca polym4decanedioatocobaltii
AT mollicanardoviviana polym4decanedioatocobaltii

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