4,4′-{[1,2-Phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate

In the title solvate, C(22)H(18)O(6)·2C(3)H(7)NO, the complete dicarboxylic acid molecule is generated by a crystallographic twofold axis, which bisects the central benzene ring and one N,N-di­methyl­formamide solvent mol­ecule. The dihedral angle between the central and pendant benzene rings is 54....

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Autores principales: Qiu, Zhen-Zhe, Jing, Bi, Li, Qiu-Xia, Zhu, Ai-Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011299/
https://www.ncbi.nlm.nih.gov/pubmed/24860345
http://dx.doi.org/10.1107/S1600536814006795
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author Qiu, Zhen-Zhe
Jing, Bi
Li, Qiu-Xia
Zhu, Ai-Xin
author_facet Qiu, Zhen-Zhe
Jing, Bi
Li, Qiu-Xia
Zhu, Ai-Xin
author_sort Qiu, Zhen-Zhe
collection PubMed
description In the title solvate, C(22)H(18)O(6)·2C(3)H(7)NO, the complete dicarboxylic acid molecule is generated by a crystallographic twofold axis, which bisects the central benzene ring and one N,N-di­methyl­formamide solvent mol­ecule. The dihedral angle between the central and pendant benzene rings is 54.53 (5)° while that between the pendant rings is 45.44 (5)°. In the crystal, the acid molecules are linked to the solvent molecules via O—H⋯O and weak C—H⋯O hydrogen bonds. Further weak C—H⋯O inter­actions link adjacent acid mol­ecules into a three-dimensional network.
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spelling pubmed-40112992014-05-23 4,4′-{[1,2-Phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate Qiu, Zhen-Zhe Jing, Bi Li, Qiu-Xia Zhu, Ai-Xin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title solvate, C(22)H(18)O(6)·2C(3)H(7)NO, the complete dicarboxylic acid molecule is generated by a crystallographic twofold axis, which bisects the central benzene ring and one N,N-di­methyl­formamide solvent mol­ecule. The dihedral angle between the central and pendant benzene rings is 54.53 (5)° while that between the pendant rings is 45.44 (5)°. In the crystal, the acid molecules are linked to the solvent molecules via O—H⋯O and weak C—H⋯O hydrogen bonds. Further weak C—H⋯O inter­actions link adjacent acid mol­ecules into a three-dimensional network. International Union of Crystallography 2014-04-12 /pmc/articles/PMC4011299/ /pubmed/24860345 http://dx.doi.org/10.1107/S1600536814006795 Text en © Qiu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Qiu, Zhen-Zhe
Jing, Bi
Li, Qiu-Xia
Zhu, Ai-Xin
4,4′-{[1,2-Phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate
title 4,4′-{[1,2-Phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate
title_full 4,4′-{[1,2-Phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate
title_fullStr 4,4′-{[1,2-Phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate
title_full_unstemmed 4,4′-{[1,2-Phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate
title_short 4,4′-{[1,2-Phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate
title_sort 4,4′-{[1,2-phenyl­enebis(methyl­ene)]bis­(­oxy)}di­benzoic acid di­methyl­formamide disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011299/
https://www.ncbi.nlm.nih.gov/pubmed/24860345
http://dx.doi.org/10.1107/S1600536814006795
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