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(E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol
The title Schiff base compound, C(15)H(15)N(3)O(3), crystallizes with two molecules (A and B) in the asymmetric unit. Each molecule adopts an E conformation around the C= N imine bond. The two molecules have minor differences in their conformations. In molecule A, the dihedral angle between the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011306/ https://www.ncbi.nlm.nih.gov/pubmed/24860394 http://dx.doi.org/10.1107/S160053681400871X |
Sumario: | The title Schiff base compound, C(15)H(15)N(3)O(3), crystallizes with two molecules (A and B) in the asymmetric unit. Each molecule adopts an E conformation around the C= N imine bond. The two molecules have minor differences in their conformations. In molecule A, the dihedral angle between the nitro group and its benzene ring is 2.1 (2)° and that between the two benzene rings is 0.88 (7)°, while the corresponding angles for molecule B are 5.7 (1) and 2.45 (6)°, respectively. In each molecule, there is an intramolecular O—H⋯N hydrogen bond. In the crystal, inversion-related molecules are linked via O—H⋯O hydrogen bonds forming A–A and B–B dimers. These dimers are linked via C—H⋯O hydrogen bonds involving the nitro O atoms, forming A–A–A and B–B–B slabs that lie parallel to one another and to (010). |
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