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(E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol
The title Schiff base compound, C(15)H(15)N(3)O(3), crystallizes with two molecules (A and B) in the asymmetric unit. Each molecule adopts an E conformation around the C= N imine bond. The two molecules have minor differences in their conformations. In molecule A, the dihedral angle between the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011306/ https://www.ncbi.nlm.nih.gov/pubmed/24860394 http://dx.doi.org/10.1107/S160053681400871X |
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author | Hijji, Yousef Butcher, Ray J. Jasinski, Jerry P. |
author_facet | Hijji, Yousef Butcher, Ray J. Jasinski, Jerry P. |
author_sort | Hijji, Yousef |
collection | PubMed |
description | The title Schiff base compound, C(15)H(15)N(3)O(3), crystallizes with two molecules (A and B) in the asymmetric unit. Each molecule adopts an E conformation around the C= N imine bond. The two molecules have minor differences in their conformations. In molecule A, the dihedral angle between the nitro group and its benzene ring is 2.1 (2)° and that between the two benzene rings is 0.88 (7)°, while the corresponding angles for molecule B are 5.7 (1) and 2.45 (6)°, respectively. In each molecule, there is an intramolecular O—H⋯N hydrogen bond. In the crystal, inversion-related molecules are linked via O—H⋯O hydrogen bonds forming A–A and B–B dimers. These dimers are linked via C—H⋯O hydrogen bonds involving the nitro O atoms, forming A–A–A and B–B–B slabs that lie parallel to one another and to (010). |
format | Online Article Text |
id | pubmed-4011306 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40113062014-05-23 (E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol Hijji, Yousef Butcher, Ray J. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(15)H(15)N(3)O(3), crystallizes with two molecules (A and B) in the asymmetric unit. Each molecule adopts an E conformation around the C= N imine bond. The two molecules have minor differences in their conformations. In molecule A, the dihedral angle between the nitro group and its benzene ring is 2.1 (2)° and that between the two benzene rings is 0.88 (7)°, while the corresponding angles for molecule B are 5.7 (1) and 2.45 (6)°, respectively. In each molecule, there is an intramolecular O—H⋯N hydrogen bond. In the crystal, inversion-related molecules are linked via O—H⋯O hydrogen bonds forming A–A and B–B dimers. These dimers are linked via C—H⋯O hydrogen bonds involving the nitro O atoms, forming A–A–A and B–B–B slabs that lie parallel to one another and to (010). International Union of Crystallography 2014-04-26 /pmc/articles/PMC4011306/ /pubmed/24860394 http://dx.doi.org/10.1107/S160053681400871X Text en © Hijji et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hijji, Yousef Butcher, Ray J. Jasinski, Jerry P. (E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol |
title | (E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol |
title_full | (E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol |
title_fullStr | (E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol |
title_full_unstemmed | (E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol |
title_short | (E)-2-{[4-(Dimethylamino)benzylidene]amino}-5-nitrophenol |
title_sort | (e)-2-{[4-(dimethylamino)benzylidene]amino}-5-nitrophenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011306/ https://www.ncbi.nlm.nih.gov/pubmed/24860394 http://dx.doi.org/10.1107/S160053681400871X |
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