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Bis[bis(2,2′-bipyridine-κ(2) N,N′)(carbonato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate
The complex cation of the title compound, [Co(CO(3))(C(10)H(8)N(2))(2)](2)(C(12)H(10)N(2)O(6))·6H(2)O, contains a Co(III) atom with a distorted octahedral coordination environment formed by four N atoms from two bidentate 2,2′-bipyridine ligands and one bidentate carbonate anion. The asymmetric un...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011312/ https://www.ncbi.nlm.nih.gov/pubmed/24860299 http://dx.doi.org/10.1107/S160053681400631X |
Sumario: | The complex cation of the title compound, [Co(CO(3))(C(10)H(8)N(2))(2)](2)(C(12)H(10)N(2)O(6))·6H(2)O, contains a Co(III) atom with a distorted octahedral coordination environment formed by four N atoms from two bidentate 2,2′-bipyridine ligands and one bidentate carbonate anion. The asymmetric unit is completed by one-half of the 2-({4-[(carboxylatomethyl)carbamoyl]phenyl}formamido)acetate dianion, which is located on a centre of inversion, and by three water molecules. Two [Co(CO(3))(C(10)H(8)N(2))(2)](+) cations are connected through C—H⋯O contacts by the uncoordinating anions. The aromatic rings of the 2,2′-bipyridine ligands and diacetate anions are involved in π–π stacking and C—H⋯π interactions. The centroid–centroid distances are in the range 3.4898 (4)–3.6384 (5) Å. The crystal structure is stabilized by further O—H⋯O and N—H⋯O hydrogen bonds, which give rise to a three-dimensional supramolecular network. |
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