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Bis[bis(2,2′-bipyridine-κ(2) N,N′)(carbonato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate
The complex cation of the title compound, [Co(CO(3))(C(10)H(8)N(2))(2)](2)(C(12)H(10)N(2)O(6))·6H(2)O, contains a Co(III) atom with a distorted octahedral coordination environment formed by four N atoms from two bidentate 2,2′-bipyridine ligands and one bidentate carbonate anion. The asymmetric un...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011312/ https://www.ncbi.nlm.nih.gov/pubmed/24860299 http://dx.doi.org/10.1107/S160053681400631X |
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author | Pook, Niels-Patrick Gjikaj, Mimoza Adam, Arnold |
author_facet | Pook, Niels-Patrick Gjikaj, Mimoza Adam, Arnold |
author_sort | Pook, Niels-Patrick |
collection | PubMed |
description | The complex cation of the title compound, [Co(CO(3))(C(10)H(8)N(2))(2)](2)(C(12)H(10)N(2)O(6))·6H(2)O, contains a Co(III) atom with a distorted octahedral coordination environment formed by four N atoms from two bidentate 2,2′-bipyridine ligands and one bidentate carbonate anion. The asymmetric unit is completed by one-half of the 2-({4-[(carboxylatomethyl)carbamoyl]phenyl}formamido)acetate dianion, which is located on a centre of inversion, and by three water molecules. Two [Co(CO(3))(C(10)H(8)N(2))(2)](+) cations are connected through C—H⋯O contacts by the uncoordinating anions. The aromatic rings of the 2,2′-bipyridine ligands and diacetate anions are involved in π–π stacking and C—H⋯π interactions. The centroid–centroid distances are in the range 3.4898 (4)–3.6384 (5) Å. The crystal structure is stabilized by further O—H⋯O and N—H⋯O hydrogen bonds, which give rise to a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-4011312 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40113122014-05-23 Bis[bis(2,2′-bipyridine-κ(2) N,N′)(carbonato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate Pook, Niels-Patrick Gjikaj, Mimoza Adam, Arnold Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex cation of the title compound, [Co(CO(3))(C(10)H(8)N(2))(2)](2)(C(12)H(10)N(2)O(6))·6H(2)O, contains a Co(III) atom with a distorted octahedral coordination environment formed by four N atoms from two bidentate 2,2′-bipyridine ligands and one bidentate carbonate anion. The asymmetric unit is completed by one-half of the 2-({4-[(carboxylatomethyl)carbamoyl]phenyl}formamido)acetate dianion, which is located on a centre of inversion, and by three water molecules. Two [Co(CO(3))(C(10)H(8)N(2))(2)](+) cations are connected through C—H⋯O contacts by the uncoordinating anions. The aromatic rings of the 2,2′-bipyridine ligands and diacetate anions are involved in π–π stacking and C—H⋯π interactions. The centroid–centroid distances are in the range 3.4898 (4)–3.6384 (5) Å. The crystal structure is stabilized by further O—H⋯O and N—H⋯O hydrogen bonds, which give rise to a three-dimensional supramolecular network. International Union of Crystallography 2014-04-02 /pmc/articles/PMC4011312/ /pubmed/24860299 http://dx.doi.org/10.1107/S160053681400631X Text en © Pook et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Pook, Niels-Patrick Gjikaj, Mimoza Adam, Arnold Bis[bis(2,2′-bipyridine-κ(2) N,N′)(carbonato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate |
title | Bis[bis(2,2′-bipyridine-κ(2)
N,N′)(carbonato-κ(2)
O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate |
title_full | Bis[bis(2,2′-bipyridine-κ(2)
N,N′)(carbonato-κ(2)
O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate |
title_fullStr | Bis[bis(2,2′-bipyridine-κ(2)
N,N′)(carbonato-κ(2)
O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate |
title_full_unstemmed | Bis[bis(2,2′-bipyridine-κ(2)
N,N′)(carbonato-κ(2)
O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate |
title_short | Bis[bis(2,2′-bipyridine-κ(2)
N,N′)(carbonato-κ(2)
O,O′)cobalt(III)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate |
title_sort | bis[bis(2,2′-bipyridine-κ(2)
n,n′)(carbonato-κ(2)
o,o′)cobalt(iii)] 2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetate hexahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011312/ https://www.ncbi.nlm.nih.gov/pubmed/24860299 http://dx.doi.org/10.1107/S160053681400631X |
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