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Bis[bis­(2,2′-bi­pyridine-κ(2) N,N′)(carbon­ato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate

The complex cation of the title compound, [Co(CO(3))(C(10)H(8)N(2))(2)](2)(C(12)H(10)N(2)O(6))·6H(2)O, contains a Co(III) atom with a distorted octa­hedral coordination environment formed by four N atoms from two bidentate 2,2′-bi­pyridine ligands and one bidentate carbonate anion. The asymmetric un...

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Detalles Bibliográficos
Autores principales: Pook, Niels-Patrick, Gjikaj, Mimoza, Adam, Arnold
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011312/
https://www.ncbi.nlm.nih.gov/pubmed/24860299
http://dx.doi.org/10.1107/S160053681400631X
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author Pook, Niels-Patrick
Gjikaj, Mimoza
Adam, Arnold
author_facet Pook, Niels-Patrick
Gjikaj, Mimoza
Adam, Arnold
author_sort Pook, Niels-Patrick
collection PubMed
description The complex cation of the title compound, [Co(CO(3))(C(10)H(8)N(2))(2)](2)(C(12)H(10)N(2)O(6))·6H(2)O, contains a Co(III) atom with a distorted octa­hedral coordination environment formed by four N atoms from two bidentate 2,2′-bi­pyridine ligands and one bidentate carbonate anion. The asymmetric unit is completed by one-half of the 2-({4-[(carboxyl­atometh­yl)carbamo­yl]phen­yl}formamido)­acetate dianion, which is located on a centre of inversion, and by three water mol­ecules. Two [Co(CO(3))(C(10)H(8)N(2))(2)](+) cations are connected through C—H⋯O contacts by the uncoordinating anions. The aromatic rings of the 2,2′-bi­pyridine ligands and di­acetate anions are involved in π–π stacking and C—H⋯π inter­actions. The centroid–centroid distances are in the range 3.4898 (4)–3.6384 (5) Å. The crystal structure is stabilized by further O—H⋯O and N—H⋯O hydrogen bonds, which give rise to a three-dimensional supra­molecular network.
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spelling pubmed-40113122014-05-23 Bis[bis­(2,2′-bi­pyridine-κ(2) N,N′)(carbon­ato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate Pook, Niels-Patrick Gjikaj, Mimoza Adam, Arnold Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex cation of the title compound, [Co(CO(3))(C(10)H(8)N(2))(2)](2)(C(12)H(10)N(2)O(6))·6H(2)O, contains a Co(III) atom with a distorted octa­hedral coordination environment formed by four N atoms from two bidentate 2,2′-bi­pyridine ligands and one bidentate carbonate anion. The asymmetric unit is completed by one-half of the 2-({4-[(carboxyl­atometh­yl)carbamo­yl]phen­yl}formamido)­acetate dianion, which is located on a centre of inversion, and by three water mol­ecules. Two [Co(CO(3))(C(10)H(8)N(2))(2)](+) cations are connected through C—H⋯O contacts by the uncoordinating anions. The aromatic rings of the 2,2′-bi­pyridine ligands and di­acetate anions are involved in π–π stacking and C—H⋯π inter­actions. The centroid–centroid distances are in the range 3.4898 (4)–3.6384 (5) Å. The crystal structure is stabilized by further O—H⋯O and N—H⋯O hydrogen bonds, which give rise to a three-dimensional supra­molecular network. International Union of Crystallography 2014-04-02 /pmc/articles/PMC4011312/ /pubmed/24860299 http://dx.doi.org/10.1107/S160053681400631X Text en © Pook et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pook, Niels-Patrick
Gjikaj, Mimoza
Adam, Arnold
Bis[bis­(2,2′-bi­pyridine-κ(2) N,N′)(carbon­ato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate
title Bis[bis­(2,2′-bi­pyridine-κ(2) N,N′)(carbon­ato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate
title_full Bis[bis­(2,2′-bi­pyridine-κ(2) N,N′)(carbon­ato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate
title_fullStr Bis[bis­(2,2′-bi­pyridine-κ(2) N,N′)(carbon­ato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate
title_full_unstemmed Bis[bis­(2,2′-bi­pyridine-κ(2) N,N′)(carbon­ato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate
title_short Bis[bis­(2,2′-bi­pyridine-κ(2) N,N′)(carbon­ato-κ(2) O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate
title_sort bis[bis­(2,2′-bi­pyridine-κ(2) n,n′)(carbon­ato-κ(2) o,o′)cobalt(iii)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011312/
https://www.ncbi.nlm.nih.gov/pubmed/24860299
http://dx.doi.org/10.1107/S160053681400631X
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