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Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) N,N′)mercury(II)

In the mononuclear title complex, [HgCl(2)(C(16)H(12)N(2)O)], synthesized from the phenolic Schiff base 4-[(quinolin-2-yl­methyl­idene)amino]­phenol (QMAP), the coordination geometry around Hg(2+) is distorted tetra­hedral, comprising two Cl atoms [Hg—Cl = 2.3565 (12) and 2.5219 (12) Å] and two N-at...

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Autores principales: Faizi, Md. Serajul Haque, Sen, Pratik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011313/
https://www.ncbi.nlm.nih.gov/pubmed/24860307
http://dx.doi.org/10.1107/S1600536814007077
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author Faizi, Md. Serajul Haque
Sen, Pratik
author_facet Faizi, Md. Serajul Haque
Sen, Pratik
author_sort Faizi, Md. Serajul Haque
collection PubMed
description In the mononuclear title complex, [HgCl(2)(C(16)H(12)N(2)O)], synthesized from the phenolic Schiff base 4-[(quinolin-2-yl­methyl­idene)amino]­phenol (QMAP), the coordination geometry around Hg(2+) is distorted tetra­hedral, comprising two Cl atoms [Hg—Cl = 2.3565 (12) and 2.5219 (12) Å] and two N-atom donors from the QMAP ligand, viz. one imine and the other quinoline [Hg—N = 2.392 (2) and 2.237 (2) Å, respectively]. In the crystal, O—H⋯Cl hydrogen bonds generate a chain structure extending along the c-axis direction. Weak C—H⋯Cl and π–π stacking inter­actions [minimum ring centroid separation = 3.641 (3) Å] give an overall layered structure lying parallel to (001).
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spelling pubmed-40113132014-05-23 Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) N,N′)mercury(II) Faizi, Md. Serajul Haque Sen, Pratik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [HgCl(2)(C(16)H(12)N(2)O)], synthesized from the phenolic Schiff base 4-[(quinolin-2-yl­methyl­idene)amino]­phenol (QMAP), the coordination geometry around Hg(2+) is distorted tetra­hedral, comprising two Cl atoms [Hg—Cl = 2.3565 (12) and 2.5219 (12) Å] and two N-atom donors from the QMAP ligand, viz. one imine and the other quinoline [Hg—N = 2.392 (2) and 2.237 (2) Å, respectively]. In the crystal, O—H⋯Cl hydrogen bonds generate a chain structure extending along the c-axis direction. Weak C—H⋯Cl and π–π stacking inter­actions [minimum ring centroid separation = 3.641 (3) Å] give an overall layered structure lying parallel to (001). International Union of Crystallography 2014-04-09 /pmc/articles/PMC4011313/ /pubmed/24860307 http://dx.doi.org/10.1107/S1600536814007077 Text en © Faizi and Sen 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Faizi, Md. Serajul Haque
Sen, Pratik
Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) N,N′)mercury(II)
title Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) N,N′)mercury(II)
title_full Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) N,N′)mercury(II)
title_fullStr Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) N,N′)mercury(II)
title_full_unstemmed Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) N,N′)mercury(II)
title_short Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) N,N′)mercury(II)
title_sort di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-κ(2) n,n′)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011313/
https://www.ncbi.nlm.nih.gov/pubmed/24860307
http://dx.doi.org/10.1107/S1600536814007077
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