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Dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2) N,N′)mercury(II)
In the mononuclear title complex, [HgCl(2)(C(16)H(12)N(2)O)], synthesized from the phenolic Schiff base 4-[(quinolin-2-ylmethylidene)amino]phenol (QMAP), the coordination geometry around Hg(2+) is distorted tetrahedral, comprising two Cl atoms [Hg—Cl = 2.3565 (12) and 2.5219 (12) Å] and two N-at...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011313/ https://www.ncbi.nlm.nih.gov/pubmed/24860307 http://dx.doi.org/10.1107/S1600536814007077 |
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author | Faizi, Md. Serajul Haque Sen, Pratik |
author_facet | Faizi, Md. Serajul Haque Sen, Pratik |
author_sort | Faizi, Md. Serajul Haque |
collection | PubMed |
description | In the mononuclear title complex, [HgCl(2)(C(16)H(12)N(2)O)], synthesized from the phenolic Schiff base 4-[(quinolin-2-ylmethylidene)amino]phenol (QMAP), the coordination geometry around Hg(2+) is distorted tetrahedral, comprising two Cl atoms [Hg—Cl = 2.3565 (12) and 2.5219 (12) Å] and two N-atom donors from the QMAP ligand, viz. one imine and the other quinoline [Hg—N = 2.392 (2) and 2.237 (2) Å, respectively]. In the crystal, O—H⋯Cl hydrogen bonds generate a chain structure extending along the c-axis direction. Weak C—H⋯Cl and π–π stacking interactions [minimum ring centroid separation = 3.641 (3) Å] give an overall layered structure lying parallel to (001). |
format | Online Article Text |
id | pubmed-4011313 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40113132014-05-23 Dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2) N,N′)mercury(II) Faizi, Md. Serajul Haque Sen, Pratik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [HgCl(2)(C(16)H(12)N(2)O)], synthesized from the phenolic Schiff base 4-[(quinolin-2-ylmethylidene)amino]phenol (QMAP), the coordination geometry around Hg(2+) is distorted tetrahedral, comprising two Cl atoms [Hg—Cl = 2.3565 (12) and 2.5219 (12) Å] and two N-atom donors from the QMAP ligand, viz. one imine and the other quinoline [Hg—N = 2.392 (2) and 2.237 (2) Å, respectively]. In the crystal, O—H⋯Cl hydrogen bonds generate a chain structure extending along the c-axis direction. Weak C—H⋯Cl and π–π stacking interactions [minimum ring centroid separation = 3.641 (3) Å] give an overall layered structure lying parallel to (001). International Union of Crystallography 2014-04-09 /pmc/articles/PMC4011313/ /pubmed/24860307 http://dx.doi.org/10.1107/S1600536814007077 Text en © Faizi and Sen 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Faizi, Md. Serajul Haque Sen, Pratik Dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2) N,N′)mercury(II) |
title | Dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2)
N,N′)mercury(II) |
title_full | Dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2)
N,N′)mercury(II) |
title_fullStr | Dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2)
N,N′)mercury(II) |
title_full_unstemmed | Dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2)
N,N′)mercury(II) |
title_short | Dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2)
N,N′)mercury(II) |
title_sort | dichlorido(4-{[(quinolin-2-yl)methylidene]amino}phenol-κ(2)
n,n′)mercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011313/ https://www.ncbi.nlm.nih.gov/pubmed/24860307 http://dx.doi.org/10.1107/S1600536814007077 |
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