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1-(4-Bromo­benz­yl)-2-(4-bromo­phen­yl)-1H-benzimidazole

There are two mol­ecules in the asymmetric unit of the title compound, C(20)H(14)Br(2)N(2). In the first, the dihedral angles between the mean plane of the benzimidazole group and those of the 4-bromo­benzyl and 4-chloro­phenyl groups are 50.72 (17) and 71.29 (16)°, respectively, while the correspon...

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Detalles Bibliográficos
Autores principales: Ma, Hua-Jun, Qu, Zhi-Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011315/
https://www.ncbi.nlm.nih.gov/pubmed/24860402
http://dx.doi.org/10.1107/S1600536814009076
Descripción
Sumario:There are two mol­ecules in the asymmetric unit of the title compound, C(20)H(14)Br(2)N(2). In the first, the dihedral angles between the mean plane of the benzimidazole group and those of the 4-bromo­benzyl and 4-chloro­phenyl groups are 50.72 (17) and 71.29 (16)°, respectively, while the corresponding angles in the second mol­ecule are 42.09 (16) and 89.05 (17)°. The 4-bromo­benzyl and 4-bromo­phenyl groups make an angle of 68.1 (2) and 85.1 (21)° with each other in the two mol­ecules. In the crystal, weak C—H⋯N and C—H⋯Br hydrogen bonds link the mol­ecules along the c-axis direction. Br⋯Br inter­actions [3.5733 (9)Å] are also observed.