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Palladium Hydride Promoted Stereoselective Isomerization of Unactivated Di(exo)methylenes to Endocyclic Dienes

[Image: see text] The exomethylenes of 2,6-disubstituted bicyclo[3.3.1]nonan-9-ones 2 are readily isomerized over a palladium catalyst under an atmosphere of hydrogen to predominantly form the isomer 3 with C(2) symmetry with very little formation of the analogous product with C(s) symmetry. A hydro...

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Detalles Bibliográficos
Autores principales:	Jung, Michael E., Lee, Gloria S., Pham, Hung V., Houk, K. N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4018140/ https://www.ncbi.nlm.nih.gov/pubmed/24720691 http://dx.doi.org/10.1021/ol500710v

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